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A top-down design for easy gram scale synthesis of melem nano rectangular prisms with improved surface area
An unprecedented top-down design for the preparation of melem by 1 h stirring of melamine-based g-C(3)N(4) in 80 °C concentrated sulfuric acid (95–98%) was discovered. The melem product was formed selectively as a monomer on the gram scale without the need for controlled conditions, inert atmosphere...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9044278/ https://www.ncbi.nlm.nih.gov/pubmed/35493241 http://dx.doi.org/10.1039/d1ra07440g |
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author | Nikookar, Mahsa Rezaeifard, Abdolreza Maasoumeh Jafarpour, Grzhegorzhevskii, Kirill V. Ostroushko, Alexander A. |
author_facet | Nikookar, Mahsa Rezaeifard, Abdolreza Maasoumeh Jafarpour, Grzhegorzhevskii, Kirill V. Ostroushko, Alexander A. |
author_sort | Nikookar, Mahsa |
collection | PubMed |
description | An unprecedented top-down design for the preparation of melem by 1 h stirring of melamine-based g-C(3)N(4) in 80 °C concentrated sulfuric acid (95–98%) was discovered. The melem product was formed selectively as a monomer on the gram scale without the need for controlled conditions, inert atmosphere, and a special purification technique. The as-prepared air-stable melem showed a distinctive nano rectangular prism morphology that possesses a larger surface area than the melems achieved by traditional bottom-up designs making it a promising candidate for catalysis and adsorption processes. |
format | Online Article Text |
id | pubmed-9044278 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90442782022-04-28 A top-down design for easy gram scale synthesis of melem nano rectangular prisms with improved surface area Nikookar, Mahsa Rezaeifard, Abdolreza Maasoumeh Jafarpour, Grzhegorzhevskii, Kirill V. Ostroushko, Alexander A. RSC Adv Chemistry An unprecedented top-down design for the preparation of melem by 1 h stirring of melamine-based g-C(3)N(4) in 80 °C concentrated sulfuric acid (95–98%) was discovered. The melem product was formed selectively as a monomer on the gram scale without the need for controlled conditions, inert atmosphere, and a special purification technique. The as-prepared air-stable melem showed a distinctive nano rectangular prism morphology that possesses a larger surface area than the melems achieved by traditional bottom-up designs making it a promising candidate for catalysis and adsorption processes. The Royal Society of Chemistry 2021-12-03 /pmc/articles/PMC9044278/ /pubmed/35493241 http://dx.doi.org/10.1039/d1ra07440g Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Nikookar, Mahsa Rezaeifard, Abdolreza Maasoumeh Jafarpour, Grzhegorzhevskii, Kirill V. Ostroushko, Alexander A. A top-down design for easy gram scale synthesis of melem nano rectangular prisms with improved surface area |
title | A top-down design for easy gram scale synthesis of melem nano rectangular prisms with improved surface area |
title_full | A top-down design for easy gram scale synthesis of melem nano rectangular prisms with improved surface area |
title_fullStr | A top-down design for easy gram scale synthesis of melem nano rectangular prisms with improved surface area |
title_full_unstemmed | A top-down design for easy gram scale synthesis of melem nano rectangular prisms with improved surface area |
title_short | A top-down design for easy gram scale synthesis of melem nano rectangular prisms with improved surface area |
title_sort | top-down design for easy gram scale synthesis of melem nano rectangular prisms with improved surface area |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9044278/ https://www.ncbi.nlm.nih.gov/pubmed/35493241 http://dx.doi.org/10.1039/d1ra07440g |
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