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Matrix-dispersed magnetic molecularly-imprinted polyaniline for the effective removal of chlorpyrifos pesticide from contaminated water

We report a new adsorbent nanocomposite material based on matrix-dispersed superparamagnetic iron oxide nanoparticles (SPIONs) in molecularly-imprinted polyaniline for the removal of chlorpyrifos (CPF), a hazardous organophosphate pesticide, from water. The synthesized magnetic molecularly-imprinted...

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Autores principales: Saad, Hadeel, Nour El-Dien, F. A., El-Gamel, Nadia E. A., Abo Dena, Ahmed S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9044561/
https://www.ncbi.nlm.nih.gov/pubmed/35494104
http://dx.doi.org/10.1039/d1ra07833j
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author Saad, Hadeel
Nour El-Dien, F. A.
El-Gamel, Nadia E. A.
Abo Dena, Ahmed S.
author_facet Saad, Hadeel
Nour El-Dien, F. A.
El-Gamel, Nadia E. A.
Abo Dena, Ahmed S.
author_sort Saad, Hadeel
collection PubMed
description We report a new adsorbent nanocomposite material based on matrix-dispersed superparamagnetic iron oxide nanoparticles (SPIONs) in molecularly-imprinted polyaniline for the removal of chlorpyrifos (CPF), a hazardous organophosphate pesticide, from water. The synthesized magnetic molecularly-imprinted polymer (MMIP) was characterized by FTIR spectroscopy, XRD, magnetic susceptibility, DLS, zeta potential measurement, SEM and high-resolution TEM imaging. The average size of the naked SPIONs ranges from 15 to 30 nm according to the high-resolution TEM analysis. Moreover, the adsorption kinetics, thermodynamic parameters (ΔG, ΔH and ΔS), adsorption isotherms and rebinding conditions were investigated in detail. The proposed MMIP has an imprinting factor of 1.64. In addition, it showed a high experimental adsorption capacity of 1.77 mg g(−1) and a removal efficiency of nearly 80%. The fabricated MMIP material demonstrated excellent magnetic susceptibility allowing for easy separation using an external magnetic field. The adsorption mechanism of CPF onto the MMIP adsorbent followed the second-order kinetics model and fitted to the Temkin adsorption isotherm. By studying the adsorption thermodynamics, negative ΔG values (−1.955 kJ mol(−1) at room temperature) were obtained revealing that the adsorption process is spontaneous. Furthermore, the maximum adsorption capacity was obtained at room temperature (ca. 303 K), neutral pH and using a high CPF concentration.
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spelling pubmed-90445612022-04-28 Matrix-dispersed magnetic molecularly-imprinted polyaniline for the effective removal of chlorpyrifos pesticide from contaminated water Saad, Hadeel Nour El-Dien, F. A. El-Gamel, Nadia E. A. Abo Dena, Ahmed S. RSC Adv Chemistry We report a new adsorbent nanocomposite material based on matrix-dispersed superparamagnetic iron oxide nanoparticles (SPIONs) in molecularly-imprinted polyaniline for the removal of chlorpyrifos (CPF), a hazardous organophosphate pesticide, from water. The synthesized magnetic molecularly-imprinted polymer (MMIP) was characterized by FTIR spectroscopy, XRD, magnetic susceptibility, DLS, zeta potential measurement, SEM and high-resolution TEM imaging. The average size of the naked SPIONs ranges from 15 to 30 nm according to the high-resolution TEM analysis. Moreover, the adsorption kinetics, thermodynamic parameters (ΔG, ΔH and ΔS), adsorption isotherms and rebinding conditions were investigated in detail. The proposed MMIP has an imprinting factor of 1.64. In addition, it showed a high experimental adsorption capacity of 1.77 mg g(−1) and a removal efficiency of nearly 80%. The fabricated MMIP material demonstrated excellent magnetic susceptibility allowing for easy separation using an external magnetic field. The adsorption mechanism of CPF onto the MMIP adsorbent followed the second-order kinetics model and fitted to the Temkin adsorption isotherm. By studying the adsorption thermodynamics, negative ΔG values (−1.955 kJ mol(−1) at room temperature) were obtained revealing that the adsorption process is spontaneous. Furthermore, the maximum adsorption capacity was obtained at room temperature (ca. 303 K), neutral pH and using a high CPF concentration. The Royal Society of Chemistry 2021-12-14 /pmc/articles/PMC9044561/ /pubmed/35494104 http://dx.doi.org/10.1039/d1ra07833j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Saad, Hadeel
Nour El-Dien, F. A.
El-Gamel, Nadia E. A.
Abo Dena, Ahmed S.
Matrix-dispersed magnetic molecularly-imprinted polyaniline for the effective removal of chlorpyrifos pesticide from contaminated water
title Matrix-dispersed magnetic molecularly-imprinted polyaniline for the effective removal of chlorpyrifos pesticide from contaminated water
title_full Matrix-dispersed magnetic molecularly-imprinted polyaniline for the effective removal of chlorpyrifos pesticide from contaminated water
title_fullStr Matrix-dispersed magnetic molecularly-imprinted polyaniline for the effective removal of chlorpyrifos pesticide from contaminated water
title_full_unstemmed Matrix-dispersed magnetic molecularly-imprinted polyaniline for the effective removal of chlorpyrifos pesticide from contaminated water
title_short Matrix-dispersed magnetic molecularly-imprinted polyaniline for the effective removal of chlorpyrifos pesticide from contaminated water
title_sort matrix-dispersed magnetic molecularly-imprinted polyaniline for the effective removal of chlorpyrifos pesticide from contaminated water
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9044561/
https://www.ncbi.nlm.nih.gov/pubmed/35494104
http://dx.doi.org/10.1039/d1ra07833j
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