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Bis(imino)-6,7-dihydro-5H-quinoline-cobalt complexes as highly active catalysts for the formation of vinyl-terminated PE waxes; steps towards inhibiting deactivation pathways through targeted ligand design
A set of five related bis(imino)-6,7-dihydro-5H-quinoline-cobalt(ii) complexes, [2-(ArN = CPh)-8-(NAr)-C(9)H(8)N]CoCl(2) (Ar = 2,6-Me(2)C(6)H(3)Co1, 2,6-Et(2)C(6)H(3)Co2, 2,6-i-Pr(2)C(6)H(3)Co3, 2,4,6-Me(3)C(6)H(2)Co4, 2,6-Et(2)-4-MeC(6)H(2)Co5), have been synthesized in reasonable yield by the temp...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9044648/ https://www.ncbi.nlm.nih.gov/pubmed/35494135 http://dx.doi.org/10.1039/d1ra07279j |