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A low-temperature hydrothermal synthesis of submicron spherical BaF(2)

The sub-micron spherical barium fluoride (BaF(2)) was successfully synthesized via a low-temperature hydrothermal method using ethylenediamine tetraacetic acid disodium salt (EDTA-2Na) as the chelating agent. The effect of pH, the molar ratio of EDTA to Ba(2+), barium hydroxide octahydrate (Ba(OH)(2...

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Detalles Bibliográficos
Autores principales: Li, Xiao, Zhao, Yuxiang, Li, Bo, Wang, Shuxuan, Zou, Xingwu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9044683/
https://www.ncbi.nlm.nih.gov/pubmed/35494118
http://dx.doi.org/10.1039/d1ra06084h
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author Li, Xiao
Zhao, Yuxiang
Li, Bo
Wang, Shuxuan
Zou, Xingwu
author_facet Li, Xiao
Zhao, Yuxiang
Li, Bo
Wang, Shuxuan
Zou, Xingwu
author_sort Li, Xiao
collection PubMed
description The sub-micron spherical barium fluoride (BaF(2)) was successfully synthesized via a low-temperature hydrothermal method using ethylenediamine tetraacetic acid disodium salt (EDTA-2Na) as the chelating agent. The effect of pH, the molar ratio of EDTA to Ba(2+), barium hydroxide octahydrate (Ba(OH)(2)·8H(2)O) concentration, hydrofluoric acid (HF) concentration, hydrothermal temperature and time, on the formation of spherical BaF(2) were investigated. The formation mechanism of spherical BaF(2) has been proposed based on the experimental results. The results show that the spherical BaF(2), with an average size of 346.9 nm, is formed by the self-assembly of nanocubes. The optimized synthesis conditions are: pH = 14, EDTA-2Na : Ba(2+) = 1 : 1, Ba(OH)(2) concentration is 0.1 mol L(−1), HF concentration is 2.0 mol L(−1), hydrothermal temperature is 80 °C and hydrothermal time is 2.0 h. The self-assembly mechanism of the spherical secondary structure was revealed from the perspective of crystal nucleation and growth, and the important role of EDTA in the spherical BaF(2) formation is explained.
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spelling pubmed-90446832022-04-28 A low-temperature hydrothermal synthesis of submicron spherical BaF(2) Li, Xiao Zhao, Yuxiang Li, Bo Wang, Shuxuan Zou, Xingwu RSC Adv Chemistry The sub-micron spherical barium fluoride (BaF(2)) was successfully synthesized via a low-temperature hydrothermal method using ethylenediamine tetraacetic acid disodium salt (EDTA-2Na) as the chelating agent. The effect of pH, the molar ratio of EDTA to Ba(2+), barium hydroxide octahydrate (Ba(OH)(2)·8H(2)O) concentration, hydrofluoric acid (HF) concentration, hydrothermal temperature and time, on the formation of spherical BaF(2) were investigated. The formation mechanism of spherical BaF(2) has been proposed based on the experimental results. The results show that the spherical BaF(2), with an average size of 346.9 nm, is formed by the self-assembly of nanocubes. The optimized synthesis conditions are: pH = 14, EDTA-2Na : Ba(2+) = 1 : 1, Ba(OH)(2) concentration is 0.1 mol L(−1), HF concentration is 2.0 mol L(−1), hydrothermal temperature is 80 °C and hydrothermal time is 2.0 h. The self-assembly mechanism of the spherical secondary structure was revealed from the perspective of crystal nucleation and growth, and the important role of EDTA in the spherical BaF(2) formation is explained. The Royal Society of Chemistry 2021-12-16 /pmc/articles/PMC9044683/ /pubmed/35494118 http://dx.doi.org/10.1039/d1ra06084h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Li, Xiao
Zhao, Yuxiang
Li, Bo
Wang, Shuxuan
Zou, Xingwu
A low-temperature hydrothermal synthesis of submicron spherical BaF(2)
title A low-temperature hydrothermal synthesis of submicron spherical BaF(2)
title_full A low-temperature hydrothermal synthesis of submicron spherical BaF(2)
title_fullStr A low-temperature hydrothermal synthesis of submicron spherical BaF(2)
title_full_unstemmed A low-temperature hydrothermal synthesis of submicron spherical BaF(2)
title_short A low-temperature hydrothermal synthesis of submicron spherical BaF(2)
title_sort low-temperature hydrothermal synthesis of submicron spherical baf(2)
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9044683/
https://www.ncbi.nlm.nih.gov/pubmed/35494118
http://dx.doi.org/10.1039/d1ra06084h
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