Palladium mediated domino reaction: synthesis of isochromenes under aqueous medium

Isochromenes have been synthesized using palladium-catalyzed C–C and C–O bond forming reactions starting from ortho-bromo tertiary benzylic alcohols and internal acetylenes. Notably, this domino process is feasible by using the green solvent, water. The protocol exhibited a broad substrate scope and...

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Detalles Bibliográficos
Autores principales: Punia, Lavisha, Ramesh, Karu, Satyanarayana, Gedu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9047682/
https://www.ncbi.nlm.nih.gov/pubmed/35492569
http://dx.doi.org/10.1039/c9ra08792c
Descripción
Sumario:Isochromenes have been synthesized using palladium-catalyzed C–C and C–O bond forming reactions starting from ortho-bromo tertiary benzylic alcohols and internal acetylenes. Notably, this domino process is feasible by using the green solvent, water. The protocol exhibited a broad substrate scope and afforded various isochromenes.

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