Disposal of high-arsenic waste acid by the stepwise formation of gypsum and scorodite

The typical disposal of high-arsenic waste acid is at the expense of discharging a large quantity of hazardous solid waste, resulting in secondary pollution of arsenic. We propose a modified lime/ferric salt method for high-arsenic waste acid disposal by the stepwise formation of gypsum and scorodite at atmospheric pressure. The sulfuric acid in the high-arsenic waste acid is first removed by calcium carbonate generating gypsum, and then the arsenic in the solution is precipitated in form of scorodite. Gypsum with an arsenic leaching concentration below 5 mg L(−1) is obtained at a final pH of 0.5 in the calcium carbonate neutralization stage. In the second stage, the optimal conditions including a starting pH of 2.0, an Fe/As ratio of 1.5, a reaction temperature in the range of 80–90 °C and a reaction time equal to or longer than 8 hours provide an arsenic removal efficiency of 95.34% by the formation of well-crystallized and environmentally stable scorodite with grain sizes in a range of 1–5 μm. The proposed process offers a promising and facile solution for the low-cost disposal of high-arsenic waste acid in the nonferrous metallurgical industry, which enables an efficient arsenic removal with the good accessibility of chemical reagents and facilities.