Circularly polarised luminescence (CPL) control of oligopeptide–Eu(iii) hybridized luminophores by interaction with peptide side chains

Chiral oligopeptide-naphthalene/Eu(iii) hybridized luminophores emit strong circularly polarised solution-state luminescence (CPL) from Eu(iii) at 592 and 614 nm (|g(CPL)| ≤ 2.1 × 10(−2)). Although the peptide ligands have matching absolute configurations, the CPL sign is controllable by varying the...

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Autores principales: Mimura, Yuki, Sato, Takuya, Motomura, Yuki, Yoshikawa, Hiroki, Shizuma, Motohiro, Kitamatsu, Mizuki, Imai, Yoshitane
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9048765/
https://www.ncbi.nlm.nih.gov/pubmed/35496087
http://dx.doi.org/10.1039/c9ra09708b
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author Mimura, Yuki
Sato, Takuya
Motomura, Yuki
Yoshikawa, Hiroki
Shizuma, Motohiro
Kitamatsu, Mizuki
Imai, Yoshitane
author_facet Mimura, Yuki
Sato, Takuya
Motomura, Yuki
Yoshikawa, Hiroki
Shizuma, Motohiro
Kitamatsu, Mizuki
Imai, Yoshitane
author_sort Mimura, Yuki
collection PubMed
description Chiral oligopeptide-naphthalene/Eu(iii) hybridized luminophores emit strong circularly polarised solution-state luminescence (CPL) from Eu(iii) at 592 and 614 nm (|g(CPL)| ≤ 2.1 × 10(−2)). Although the peptide ligands have matching absolute configurations, the CPL sign is controllable by varying the number of naphthalene units and peptide/Eu(iii) coordination ratio.
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spelling pubmed-90487652022-04-28 Circularly polarised luminescence (CPL) control of oligopeptide–Eu(iii) hybridized luminophores by interaction with peptide side chains Mimura, Yuki Sato, Takuya Motomura, Yuki Yoshikawa, Hiroki Shizuma, Motohiro Kitamatsu, Mizuki Imai, Yoshitane RSC Adv Chemistry Chiral oligopeptide-naphthalene/Eu(iii) hybridized luminophores emit strong circularly polarised solution-state luminescence (CPL) from Eu(iii) at 592 and 614 nm (|g(CPL)| ≤ 2.1 × 10(−2)). Although the peptide ligands have matching absolute configurations, the CPL sign is controllable by varying the number of naphthalene units and peptide/Eu(iii) coordination ratio. The Royal Society of Chemistry 2020-01-14 /pmc/articles/PMC9048765/ /pubmed/35496087 http://dx.doi.org/10.1039/c9ra09708b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Mimura, Yuki
Sato, Takuya
Motomura, Yuki
Yoshikawa, Hiroki
Shizuma, Motohiro
Kitamatsu, Mizuki
Imai, Yoshitane
Circularly polarised luminescence (CPL) control of oligopeptide–Eu(iii) hybridized luminophores by interaction with peptide side chains
title Circularly polarised luminescence (CPL) control of oligopeptide–Eu(iii) hybridized luminophores by interaction with peptide side chains
title_full Circularly polarised luminescence (CPL) control of oligopeptide–Eu(iii) hybridized luminophores by interaction with peptide side chains
title_fullStr Circularly polarised luminescence (CPL) control of oligopeptide–Eu(iii) hybridized luminophores by interaction with peptide side chains
title_full_unstemmed Circularly polarised luminescence (CPL) control of oligopeptide–Eu(iii) hybridized luminophores by interaction with peptide side chains
title_short Circularly polarised luminescence (CPL) control of oligopeptide–Eu(iii) hybridized luminophores by interaction with peptide side chains
title_sort circularly polarised luminescence (cpl) control of oligopeptide–eu(iii) hybridized luminophores by interaction with peptide side chains
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9048765/
https://www.ncbi.nlm.nih.gov/pubmed/35496087
http://dx.doi.org/10.1039/c9ra09708b
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