Lychee-like TiO(2)@TiN dual-function composite material for lithium–sulfur batteries

Lithium–sulfur (Li–S) batteries are promising candidates for next generation rechargeable batteries because of their high energy density of 2600 W h kg(−1). However, the insulating nature of sulfur and Li(2)S, the “shuttle effect” of lithium polysulfides (LiPSs), and the volumetric change of sulfur electrodes limit the practical application of Li–S batteries. Here, lychee-like TiO(2)@TiN hollow spheres (LTTHS) have been developed that combine the advantages of high adsorption TiO(2) and high conductivity TiN to achieve smooth adsorption/spread/conversion of LiPSs and use them as a sulfur host material in Li–S batteries for the first time. The cathode exhibits an initial specific capacity of 1254 mA h g(−1) and a reversible capacity of 533 mA h g(−1) after 500 cycles at 0.2C, which corresponds to an average coulombic efficiency up to 99%. The cell with the LTTHS@S cathode achieved an extended lifespan of over 1000 cycles. Such good performance can be assigned to the good adsorption and catalysis of the dual-function TiO(2)@TiN composite. This work proved that the TiO(2)@TiN composite can be an attractive matrix for sulfur cathodes.