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Two-dimensional square-grid iron(ii) coordination polymers showing anion-dependent spin crossover behavior
Two Fe(ii)-based coordination polymers [Fe(tpmd)(2)(NCS)(2)]·5.5H(2)O (1) and [Fe(tpmd)(2)(NCSe)(2)]·7H(2)O (2) with the framework of square-grid type have been assembled from FeSO(4)·7H(2)O, N,N,N′,N′-tetrakis(pyridin-4-yl)methanediamine (tpmd), and KNCS/KNCSe in methanol and characterized. By util...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9049044/ https://www.ncbi.nlm.nih.gov/pubmed/35498313 http://dx.doi.org/10.1039/c9ra09782a |
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author | Shin, Jong Won Jeong, Ah Rim Jeong, Jong Hwa Zenno, Hikaru Hayami, Shinya Min, Kil Sik |
author_facet | Shin, Jong Won Jeong, Ah Rim Jeong, Jong Hwa Zenno, Hikaru Hayami, Shinya Min, Kil Sik |
author_sort | Shin, Jong Won |
collection | PubMed |
description | Two Fe(ii)-based coordination polymers [Fe(tpmd)(2)(NCS)(2)]·5.5H(2)O (1) and [Fe(tpmd)(2)(NCSe)(2)]·7H(2)O (2) with the framework of square-grid type have been assembled from FeSO(4)·7H(2)O, N,N,N′,N′-tetrakis(pyridin-4-yl)methanediamine (tpmd), and KNCS/KNCSe in methanol and characterized. By utilizing two pyridine groups of a tpmd ligand, 1 and 2 are formed in two-dimensional layered structures through coordination of octahedral iron(ii) ions with the tpmd to NCS(−)/NCSe(−) ligands in which they have a supramolecular isomorphous conformation. 1 shows a paramagnetic behavior between 2 and 300 K, while 2 exhibits two-step spin crossover (ca. 145 and 50 K) in the temperature range due to the coordination of NCSe(−) ligands. At 300 K 2 is fully high-spin state. However, at 100 K 2 becomes ca. 50% high spin and 50% low spin iron(ii) ions, which is verified by magnetic moments. In the structural analysis of 2 at 100 K, two different layers are observed with different bond distances around iron(ii) ions in which the layers are stacked alternately. |
format | Online Article Text |
id | pubmed-9049044 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90490442022-04-28 Two-dimensional square-grid iron(ii) coordination polymers showing anion-dependent spin crossover behavior Shin, Jong Won Jeong, Ah Rim Jeong, Jong Hwa Zenno, Hikaru Hayami, Shinya Min, Kil Sik RSC Adv Chemistry Two Fe(ii)-based coordination polymers [Fe(tpmd)(2)(NCS)(2)]·5.5H(2)O (1) and [Fe(tpmd)(2)(NCSe)(2)]·7H(2)O (2) with the framework of square-grid type have been assembled from FeSO(4)·7H(2)O, N,N,N′,N′-tetrakis(pyridin-4-yl)methanediamine (tpmd), and KNCS/KNCSe in methanol and characterized. By utilizing two pyridine groups of a tpmd ligand, 1 and 2 are formed in two-dimensional layered structures through coordination of octahedral iron(ii) ions with the tpmd to NCS(−)/NCSe(−) ligands in which they have a supramolecular isomorphous conformation. 1 shows a paramagnetic behavior between 2 and 300 K, while 2 exhibits two-step spin crossover (ca. 145 and 50 K) in the temperature range due to the coordination of NCSe(−) ligands. At 300 K 2 is fully high-spin state. However, at 100 K 2 becomes ca. 50% high spin and 50% low spin iron(ii) ions, which is verified by magnetic moments. In the structural analysis of 2 at 100 K, two different layers are observed with different bond distances around iron(ii) ions in which the layers are stacked alternately. The Royal Society of Chemistry 2020-01-31 /pmc/articles/PMC9049044/ /pubmed/35498313 http://dx.doi.org/10.1039/c9ra09782a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Shin, Jong Won Jeong, Ah Rim Jeong, Jong Hwa Zenno, Hikaru Hayami, Shinya Min, Kil Sik Two-dimensional square-grid iron(ii) coordination polymers showing anion-dependent spin crossover behavior |
title | Two-dimensional square-grid iron(ii) coordination polymers showing anion-dependent spin crossover behavior |
title_full | Two-dimensional square-grid iron(ii) coordination polymers showing anion-dependent spin crossover behavior |
title_fullStr | Two-dimensional square-grid iron(ii) coordination polymers showing anion-dependent spin crossover behavior |
title_full_unstemmed | Two-dimensional square-grid iron(ii) coordination polymers showing anion-dependent spin crossover behavior |
title_short | Two-dimensional square-grid iron(ii) coordination polymers showing anion-dependent spin crossover behavior |
title_sort | two-dimensional square-grid iron(ii) coordination polymers showing anion-dependent spin crossover behavior |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9049044/ https://www.ncbi.nlm.nih.gov/pubmed/35498313 http://dx.doi.org/10.1039/c9ra09782a |
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