Two-dimensional square-grid iron(ii) coordination polymers showing anion-dependent spin crossover behavior

Two Fe(ii)-based coordination polymers [Fe(tpmd)(2)(NCS)(2)]·5.5H(2)O (1) and [Fe(tpmd)(2)(NCSe)(2)]·7H(2)O (2) with the framework of square-grid type have been assembled from FeSO(4)·7H(2)O, N,N,N′,N′-tetrakis(pyridin-4-yl)methanediamine (tpmd), and KNCS/KNCSe in methanol and characterized. By util...

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Detalles Bibliográficos
Autores principales: Shin, Jong Won, Jeong, Ah Rim, Jeong, Jong Hwa, Zenno, Hikaru, Hayami, Shinya, Min, Kil Sik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9049044/
https://www.ncbi.nlm.nih.gov/pubmed/35498313
http://dx.doi.org/10.1039/c9ra09782a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9049044/
https://www.ncbi.nlm.nih.gov/pubmed/35498313
http://dx.doi.org/10.1039/c9ra09782a

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