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Two-dimensional square-grid iron(ii) coordination polymers showing anion-dependent spin crossover behavior
Two Fe(ii)-based coordination polymers [Fe(tpmd)(2)(NCS)(2)]·5.5H(2)O (1) and [Fe(tpmd)(2)(NCSe)(2)]·7H(2)O (2) with the framework of square-grid type have been assembled from FeSO(4)·7H(2)O, N,N,N′,N′-tetrakis(pyridin-4-yl)methanediamine (tpmd), and KNCS/KNCSe in methanol and characterized. By util...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9049044/ https://www.ncbi.nlm.nih.gov/pubmed/35498313 http://dx.doi.org/10.1039/c9ra09782a |