Synthesis of a GaOOH/ZnBiTaO(5) heterojunction photocatalyst with enhanced photocatalytic performance toward enrofloxacin

In this work, a GaOOH/ZnBiTaO(5) heterojunction photocatalyst was synthesized innovatively and characterization techniques including XRD, SEM-EDS, XPS, FT-IR, PL and UV-Vis DRS were carried out to analyse the structural and morphological properties of the GaOOH/ZnBiTaO(5) heterojunction photocatalyst. The GaOOH is dispersed on the surface of ZnBiTaO(5) to form a heterojunction structure according to the SEM image. The band gaps of 10 wt%, 25 wt% and 50 wt% GaOOH/ZnBiTaO(5) heterojunction photocatalysts were calculated to be 3.21 eV, 3.22 eV and 3.23 eV, respectively, which were between the band gaps of pure ZnBiTaO(5) (3.19 eV) and pure GaOOH (4.76 eV). The photocatalytic performance of the GaOOH/ZnBiTaO(5) heterojunction photocatalyst was investigated by degrading enrofloxacin under ultraviolet light. The results showed that the as-prepared 25 wt% GaOOH/ZnBiTaO(5) presented optimal photocatalytic performance and could remove 58.27% of enrofloxacin in 60 min, which was higher than that of pure ZnBiTaO(5) (53.7%) and pure GaOOH (35.4%). In addition, it was confirmed that ˙O(2)(−), h(+) and ˙OH were all the active radicals during the degradation process. Finally, the possible degradation mechanism of enrofloxacin was discussed in detail. This work provided a viable strategy for improving the photocatalytic performance of wide band gap semiconductors.