Oxidative carboxylation of olefins with CO(2): environmentally benign access to five-membered cyclic carbonates

The purpose of this focus review is to provide a comprehensive overview of the direct synthesis of five-membered cyclic carbonates via oxidative carboxylation of the corresponding olefins and carbon dioxide with particular attention on the mechanistic features of the reactions. The review is divided...

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Detalles Bibliográficos
Autores principales: Wang, Liang, Que, Sisi, Ding, Ziwei, Vessally, Esmail
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050038/
https://www.ncbi.nlm.nih.gov/pubmed/35496570
http://dx.doi.org/10.1039/c9ra10755j
Descripción
Sumario:The purpose of this focus review is to provide a comprehensive overview of the direct synthesis of five-membered cyclic carbonates via oxidative carboxylation of the corresponding olefins and carbon dioxide with particular attention on the mechanistic features of the reactions. The review is divided into two main sections. The first section is a discussion of the single-step reactions, while the second consists of an overview of one-pot, two-step sequential reactions.

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