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Effect of alcohol addition on the structure and corrosion resistance of plasma electrolytic oxidation films formed on AZ31B magnesium alloy

The effect of the addition of alcohol to a Na(3)PO(4)-based electrolyte on plasma electrolytic oxidation (PEO) of AZ31B magnesium alloy was investigated. Anodization with spark discharge was conducted in Na(3)PO(4)-based electrolyte containing various alcohols (e.g., ethanol, ethylene glycol, and gl...

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Autores principales: Asoh, Hidetaka, Asakura, Kento, Hashimoto, Hideki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050119/
https://www.ncbi.nlm.nih.gov/pubmed/35496549
http://dx.doi.org/10.1039/d0ra01154a
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author Asoh, Hidetaka
Asakura, Kento
Hashimoto, Hideki
author_facet Asoh, Hidetaka
Asakura, Kento
Hashimoto, Hideki
author_sort Asoh, Hidetaka
collection PubMed
description The effect of the addition of alcohol to a Na(3)PO(4)-based electrolyte on plasma electrolytic oxidation (PEO) of AZ31B magnesium alloy was investigated. Anodization with spark discharge was conducted in Na(3)PO(4)-based electrolyte containing various alcohols (e.g., ethanol, ethylene glycol, and glycerol) at a constant current density of 200 A m(−2) and a constant temperature of 25 °C. Voltage–time curves during the PEO process, the film structure, surface roughness, crystallographic structure, composition, corrosion resistance, and withstand voltage were investigated using various analytical equipment and electrochemical measurements. When the electrolyte containing alcohol was used, the initial bending voltage was higher than that observed using the basic electrolyte without alcohol addition, as was the oscillation voltage during the PEO process. For a given amount of electricity supplied, the addition of alcohol into the basic electrolyte tended to increase the thickness and corrosion resistance of PEO films formed while effectively reducing surface roughness. In particular, the addition of a polyhydric alcohol (i.e., ethylene glycol and glycerol) could act not only as a leveler for the formation of compact film but also as an enhancer for film qualities, such as corrosion resistance and withstand voltage. The patterns observed for Na(3)PO(4)-based electrolyte containing alcohol also hold for Na(2)SiO(3)-based electrolyte containing alcohol.
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spelling pubmed-90501192022-04-29 Effect of alcohol addition on the structure and corrosion resistance of plasma electrolytic oxidation films formed on AZ31B magnesium alloy Asoh, Hidetaka Asakura, Kento Hashimoto, Hideki RSC Adv Chemistry The effect of the addition of alcohol to a Na(3)PO(4)-based electrolyte on plasma electrolytic oxidation (PEO) of AZ31B magnesium alloy was investigated. Anodization with spark discharge was conducted in Na(3)PO(4)-based electrolyte containing various alcohols (e.g., ethanol, ethylene glycol, and glycerol) at a constant current density of 200 A m(−2) and a constant temperature of 25 °C. Voltage–time curves during the PEO process, the film structure, surface roughness, crystallographic structure, composition, corrosion resistance, and withstand voltage were investigated using various analytical equipment and electrochemical measurements. When the electrolyte containing alcohol was used, the initial bending voltage was higher than that observed using the basic electrolyte without alcohol addition, as was the oscillation voltage during the PEO process. For a given amount of electricity supplied, the addition of alcohol into the basic electrolyte tended to increase the thickness and corrosion resistance of PEO films formed while effectively reducing surface roughness. In particular, the addition of a polyhydric alcohol (i.e., ethylene glycol and glycerol) could act not only as a leveler for the formation of compact film but also as an enhancer for film qualities, such as corrosion resistance and withstand voltage. The patterns observed for Na(3)PO(4)-based electrolyte containing alcohol also hold for Na(2)SiO(3)-based electrolyte containing alcohol. The Royal Society of Chemistry 2020-03-02 /pmc/articles/PMC9050119/ /pubmed/35496549 http://dx.doi.org/10.1039/d0ra01154a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Asoh, Hidetaka
Asakura, Kento
Hashimoto, Hideki
Effect of alcohol addition on the structure and corrosion resistance of plasma electrolytic oxidation films formed on AZ31B magnesium alloy
title Effect of alcohol addition on the structure and corrosion resistance of plasma electrolytic oxidation films formed on AZ31B magnesium alloy
title_full Effect of alcohol addition on the structure and corrosion resistance of plasma electrolytic oxidation films formed on AZ31B magnesium alloy
title_fullStr Effect of alcohol addition on the structure and corrosion resistance of plasma electrolytic oxidation films formed on AZ31B magnesium alloy
title_full_unstemmed Effect of alcohol addition on the structure and corrosion resistance of plasma electrolytic oxidation films formed on AZ31B magnesium alloy
title_short Effect of alcohol addition on the structure and corrosion resistance of plasma electrolytic oxidation films formed on AZ31B magnesium alloy
title_sort effect of alcohol addition on the structure and corrosion resistance of plasma electrolytic oxidation films formed on az31b magnesium alloy
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050119/
https://www.ncbi.nlm.nih.gov/pubmed/35496549
http://dx.doi.org/10.1039/d0ra01154a
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