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Synthesis and fluorescence properties of butadiyne-linked linear and cyclic carbazole oligomers

Butadiyne-linked linear and cyclic carbazole oligomers were successfully synthesized. The intensity of the emission band in the 0–0 band of the highly planar macrocyclics decreased compared to that of the 0–1 band. Contrary to this, for larger macrocycles having reduced planarity, the intensity of t...

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Detalles Bibliográficos
Autores principales: Ogawa, Kazuya, Tanaka, Shohei, Shimura, Kyosuke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050127/
https://www.ncbi.nlm.nih.gov/pubmed/35497230
http://dx.doi.org/10.1039/d0ra00830c
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author Ogawa, Kazuya
Tanaka, Shohei
Shimura, Kyosuke
author_facet Ogawa, Kazuya
Tanaka, Shohei
Shimura, Kyosuke
author_sort Ogawa, Kazuya
collection PubMed
description Butadiyne-linked linear and cyclic carbazole oligomers were successfully synthesized. The intensity of the emission band in the 0–0 band of the highly planar macrocyclics decreased compared to that of the 0–1 band. Contrary to this, for larger macrocycles having reduced planarity, the intensity of the emission of the 0–0 band increased as in the cases of the linear compounds. This suggests that the emission color of the π-conjugated molecule can be controlled not only by the difference between the cyclic and chain structures but also by the control of the planarity, and is expected to be a new principle for molecular design in the development of fluorescent materials.
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spelling pubmed-90501272022-04-29 Synthesis and fluorescence properties of butadiyne-linked linear and cyclic carbazole oligomers Ogawa, Kazuya Tanaka, Shohei Shimura, Kyosuke RSC Adv Chemistry Butadiyne-linked linear and cyclic carbazole oligomers were successfully synthesized. The intensity of the emission band in the 0–0 band of the highly planar macrocyclics decreased compared to that of the 0–1 band. Contrary to this, for larger macrocycles having reduced planarity, the intensity of the emission of the 0–0 band increased as in the cases of the linear compounds. This suggests that the emission color of the π-conjugated molecule can be controlled not only by the difference between the cyclic and chain structures but also by the control of the planarity, and is expected to be a new principle for molecular design in the development of fluorescent materials. The Royal Society of Chemistry 2020-03-06 /pmc/articles/PMC9050127/ /pubmed/35497230 http://dx.doi.org/10.1039/d0ra00830c Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Ogawa, Kazuya
Tanaka, Shohei
Shimura, Kyosuke
Synthesis and fluorescence properties of butadiyne-linked linear and cyclic carbazole oligomers
title Synthesis and fluorescence properties of butadiyne-linked linear and cyclic carbazole oligomers
title_full Synthesis and fluorescence properties of butadiyne-linked linear and cyclic carbazole oligomers
title_fullStr Synthesis and fluorescence properties of butadiyne-linked linear and cyclic carbazole oligomers
title_full_unstemmed Synthesis and fluorescence properties of butadiyne-linked linear and cyclic carbazole oligomers
title_short Synthesis and fluorescence properties of butadiyne-linked linear and cyclic carbazole oligomers
title_sort synthesis and fluorescence properties of butadiyne-linked linear and cyclic carbazole oligomers
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050127/
https://www.ncbi.nlm.nih.gov/pubmed/35497230
http://dx.doi.org/10.1039/d0ra00830c
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AT tanakashohei synthesisandfluorescencepropertiesofbutadiynelinkedlinearandcycliccarbazoleoligomers
AT shimurakyosuke synthesisandfluorescencepropertiesofbutadiynelinkedlinearandcycliccarbazoleoligomers