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pH-Dependent transfer hydrogenation or dihydrogen release catalyzed by a [(η(6)-arene)RuCl(κ(2)-N,N-dmobpy)](+) complex: a DFT mechanistic understanding

The reaction mechanism of the pH-dependent transfer hydrogenation of a ketone or the dehydrogenation of formic acid catalyzed by a [(η(6)-arene)RuCl(κ(2)-N,N-dmobpy)](+) complex in aqueous media has been investigated using the density functional theory (DFT) method. The TM-catalyzed TH of ketones wi...

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Detalles Bibliográficos
Autores principales:	Luo, Chenguang, Li, Longfei, Yue, Xin, Li, Pengjie, Zhang, Lin, Yang, Zuoyin, Pu, Min, Cao, Zexing, Lei, Ming
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050405/ https://www.ncbi.nlm.nih.gov/pubmed/35492899 http://dx.doi.org/10.1039/c9ra10651k

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