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Experimental and computational studies of graphene oxide covalently functionalized by octylamine: electrochemical stability, hydrogen evolution, and corrosion inhibition of the AZ13 Mg alloy in 3.5% NaCl
Recently, carbon allotropes were shown to play a key role in energy harvesting and as hydrophobic coatings on metal alloys. We have designed octylamine-functionalized graphene oxide materials for energy harvesting and as an anti-corrosion coating for metal alloy protection in a 3.5% NaCl medium. The...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050467/ https://www.ncbi.nlm.nih.gov/pubmed/35495345 http://dx.doi.org/10.1039/c9ra10702a |
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author | Palaniappan, N. Cole, I. S. Kuznetsov, A. E. |
author_facet | Palaniappan, N. Cole, I. S. Kuznetsov, A. E. |
author_sort | Palaniappan, N. |
collection | PubMed |
description | Recently, carbon allotropes were shown to play a key role in energy harvesting and as hydrophobic coatings on metal alloys. We have designed octylamine-functionalized graphene oxide materials for energy harvesting and as an anti-corrosion coating for metal alloy protection in a 3.5% NaCl medium. The material has been characterized by different techniques to confirm the structure and composition of the modified graphene oxide sheet: FTIR spectroscopy, XRD, Raman spectroscopy, FESEM and TEM. The electrochemical stability and corrosion inhibition efficiency were studied by electrochemical methods. The electrochemical stability increased with an increase in the applied voltage up to 500 mV, and the corrosion inhibition efficiency was shown to be 73%. The coating stability studies showed a long stability time in the corrosion medium. |
format | Online Article Text |
id | pubmed-9050467 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90504672022-04-29 Experimental and computational studies of graphene oxide covalently functionalized by octylamine: electrochemical stability, hydrogen evolution, and corrosion inhibition of the AZ13 Mg alloy in 3.5% NaCl Palaniappan, N. Cole, I. S. Kuznetsov, A. E. RSC Adv Chemistry Recently, carbon allotropes were shown to play a key role in energy harvesting and as hydrophobic coatings on metal alloys. We have designed octylamine-functionalized graphene oxide materials for energy harvesting and as an anti-corrosion coating for metal alloy protection in a 3.5% NaCl medium. The material has been characterized by different techniques to confirm the structure and composition of the modified graphene oxide sheet: FTIR spectroscopy, XRD, Raman spectroscopy, FESEM and TEM. The electrochemical stability and corrosion inhibition efficiency were studied by electrochemical methods. The electrochemical stability increased with an increase in the applied voltage up to 500 mV, and the corrosion inhibition efficiency was shown to be 73%. The coating stability studies showed a long stability time in the corrosion medium. The Royal Society of Chemistry 2020-03-20 /pmc/articles/PMC9050467/ /pubmed/35495345 http://dx.doi.org/10.1039/c9ra10702a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Palaniappan, N. Cole, I. S. Kuznetsov, A. E. Experimental and computational studies of graphene oxide covalently functionalized by octylamine: electrochemical stability, hydrogen evolution, and corrosion inhibition of the AZ13 Mg alloy in 3.5% NaCl |
title | Experimental and computational studies of graphene oxide covalently functionalized by octylamine: electrochemical stability, hydrogen evolution, and corrosion inhibition of the AZ13 Mg alloy in 3.5% NaCl |
title_full | Experimental and computational studies of graphene oxide covalently functionalized by octylamine: electrochemical stability, hydrogen evolution, and corrosion inhibition of the AZ13 Mg alloy in 3.5% NaCl |
title_fullStr | Experimental and computational studies of graphene oxide covalently functionalized by octylamine: electrochemical stability, hydrogen evolution, and corrosion inhibition of the AZ13 Mg alloy in 3.5% NaCl |
title_full_unstemmed | Experimental and computational studies of graphene oxide covalently functionalized by octylamine: electrochemical stability, hydrogen evolution, and corrosion inhibition of the AZ13 Mg alloy in 3.5% NaCl |
title_short | Experimental and computational studies of graphene oxide covalently functionalized by octylamine: electrochemical stability, hydrogen evolution, and corrosion inhibition of the AZ13 Mg alloy in 3.5% NaCl |
title_sort | experimental and computational studies of graphene oxide covalently functionalized by octylamine: electrochemical stability, hydrogen evolution, and corrosion inhibition of the az13 mg alloy in 3.5% nacl |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050467/ https://www.ncbi.nlm.nih.gov/pubmed/35495345 http://dx.doi.org/10.1039/c9ra10702a |
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