Solvent-assisted linker exchange as a tool for the design of mixed-linker MIL-140D structured MOFs for highly selective detection of gaseous H(2)S

A MIL-140D-sdc framework has been used as a highly stable backbone for the introduction of 4,4′-azobenzene dicarboxylic acid (H(2)abdc) via solvent-assisted ligand exchange (SALE). The implemented azo groups can serve as coordination sites for copper ions. These can exchange ligands with different g...

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Autores principales: Schulz, Marcel, Marquardt, Nele, Schäfer, Malte, Heinemeyer, Thea, Schaate, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050664/
https://www.ncbi.nlm.nih.gov/pubmed/35497577
http://dx.doi.org/10.1039/d0ra01164a
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author Schulz, Marcel
Marquardt, Nele
Schäfer, Malte
Heinemeyer, Thea
Schaate, Andreas
author_facet Schulz, Marcel
Marquardt, Nele
Schäfer, Malte
Heinemeyer, Thea
Schaate, Andreas
author_sort Schulz, Marcel
collection PubMed
description A MIL-140D-sdc framework has been used as a highly stable backbone for the introduction of 4,4′-azobenzene dicarboxylic acid (H(2)abdc) via solvent-assisted ligand exchange (SALE). The implemented azo groups can serve as coordination sites for copper ions. These can exchange ligands with different gases, but show a high selectivity against H(2)S, which makes this material promising for potential sensor applications.
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spelling pubmed-90506642022-04-29 Solvent-assisted linker exchange as a tool for the design of mixed-linker MIL-140D structured MOFs for highly selective detection of gaseous H(2)S Schulz, Marcel Marquardt, Nele Schäfer, Malte Heinemeyer, Thea Schaate, Andreas RSC Adv Chemistry A MIL-140D-sdc framework has been used as a highly stable backbone for the introduction of 4,4′-azobenzene dicarboxylic acid (H(2)abdc) via solvent-assisted ligand exchange (SALE). The implemented azo groups can serve as coordination sites for copper ions. These can exchange ligands with different gases, but show a high selectivity against H(2)S, which makes this material promising for potential sensor applications. The Royal Society of Chemistry 2020-03-26 /pmc/articles/PMC9050664/ /pubmed/35497577 http://dx.doi.org/10.1039/d0ra01164a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Schulz, Marcel
Marquardt, Nele
Schäfer, Malte
Heinemeyer, Thea
Schaate, Andreas
Solvent-assisted linker exchange as a tool for the design of mixed-linker MIL-140D structured MOFs for highly selective detection of gaseous H(2)S
title Solvent-assisted linker exchange as a tool for the design of mixed-linker MIL-140D structured MOFs for highly selective detection of gaseous H(2)S
title_full Solvent-assisted linker exchange as a tool for the design of mixed-linker MIL-140D structured MOFs for highly selective detection of gaseous H(2)S
title_fullStr Solvent-assisted linker exchange as a tool for the design of mixed-linker MIL-140D structured MOFs for highly selective detection of gaseous H(2)S
title_full_unstemmed Solvent-assisted linker exchange as a tool for the design of mixed-linker MIL-140D structured MOFs for highly selective detection of gaseous H(2)S
title_short Solvent-assisted linker exchange as a tool for the design of mixed-linker MIL-140D structured MOFs for highly selective detection of gaseous H(2)S
title_sort solvent-assisted linker exchange as a tool for the design of mixed-linker mil-140d structured mofs for highly selective detection of gaseous h(2)s
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9050664/
https://www.ncbi.nlm.nih.gov/pubmed/35497577
http://dx.doi.org/10.1039/d0ra01164a
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