Synthesis of a coumarin derivative of resorcin[4]arene with solvent-controlled chirality

This paper presents the synthesis of a coumarin derivative of resorcin[4]arene (1) using a cascade thermolysis/Michael reaction. The influence of the hydrogen bonding system on the conformational rigidity and cyclochirality of the coumarin derivative of resorcin[4]arene was discussed; these properti...

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Detalles Bibliográficos
Autores principales: Szafraniec, Anna, Iwanek, Waldemar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9051107/
https://www.ncbi.nlm.nih.gov/pubmed/35492126
http://dx.doi.org/10.1039/d0ra00368a
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author Szafraniec, Anna
Iwanek, Waldemar
author_facet Szafraniec, Anna
Iwanek, Waldemar
author_sort Szafraniec, Anna
collection PubMed
description This paper presents the synthesis of a coumarin derivative of resorcin[4]arene (1) using a cascade thermolysis/Michael reaction. The influence of the hydrogen bonding system on the conformational rigidity and cyclochirality of the coumarin derivative of resorcin[4]arene was discussed; these properties depended on the proton-donor–acceptor properties of the solvent. Significant differences, which depended on the environment, in the coumarin derivative of resorcin[4]arene fluorescence were observed and discussed.
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spelling pubmed-90511072022-04-29 Synthesis of a coumarin derivative of resorcin[4]arene with solvent-controlled chirality Szafraniec, Anna Iwanek, Waldemar RSC Adv Chemistry This paper presents the synthesis of a coumarin derivative of resorcin[4]arene (1) using a cascade thermolysis/Michael reaction. The influence of the hydrogen bonding system on the conformational rigidity and cyclochirality of the coumarin derivative of resorcin[4]arene was discussed; these properties depended on the proton-donor–acceptor properties of the solvent. Significant differences, which depended on the environment, in the coumarin derivative of resorcin[4]arene fluorescence were observed and discussed. The Royal Society of Chemistry 2020-03-30 /pmc/articles/PMC9051107/ /pubmed/35492126 http://dx.doi.org/10.1039/d0ra00368a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Szafraniec, Anna
Iwanek, Waldemar
Synthesis of a coumarin derivative of resorcin[4]arene with solvent-controlled chirality
title Synthesis of a coumarin derivative of resorcin[4]arene with solvent-controlled chirality
title_full Synthesis of a coumarin derivative of resorcin[4]arene with solvent-controlled chirality
title_fullStr Synthesis of a coumarin derivative of resorcin[4]arene with solvent-controlled chirality
title_full_unstemmed Synthesis of a coumarin derivative of resorcin[4]arene with solvent-controlled chirality
title_short Synthesis of a coumarin derivative of resorcin[4]arene with solvent-controlled chirality
title_sort synthesis of a coumarin derivative of resorcin[4]arene with solvent-controlled chirality
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9051107/
https://www.ncbi.nlm.nih.gov/pubmed/35492126
http://dx.doi.org/10.1039/d0ra00368a
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