Facile synthesis of a semiconducting bithiophene-azine polymer and its application for organic thin film transistors and organic photovoltaics

A new azine polymer poly(4,4′-didodecyl-2,2′-bithiophene-azine) (PDDBTA) was synthesized in only three steps. PDDBTA showed hole mobilities of up to 4.1 × 10(−2) cm(2) V(−1) s(−1) in organic thin film transistors (OTFTs) as a p-channel material. As a donor in organic photovoltaics (OPVs), power conv...

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Autores principales: Wang, Guanlin, Kumar, Pankaj, Zhang, Zhifang, Hendsbee, Arthur D., Liu, Haitao, Li, Xu, Wang, Jinliang, Li, Yuning
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9051313/
https://www.ncbi.nlm.nih.gov/pubmed/35492137
http://dx.doi.org/10.1039/d0ra01211d
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author Wang, Guanlin
Kumar, Pankaj
Zhang, Zhifang
Hendsbee, Arthur D.
Liu, Haitao
Li, Xu
Wang, Jinliang
Li, Yuning
author_facet Wang, Guanlin
Kumar, Pankaj
Zhang, Zhifang
Hendsbee, Arthur D.
Liu, Haitao
Li, Xu
Wang, Jinliang
Li, Yuning
author_sort Wang, Guanlin
collection PubMed
description A new azine polymer poly(4,4′-didodecyl-2,2′-bithiophene-azine) (PDDBTA) was synthesized in only three steps. PDDBTA showed hole mobilities of up to 4.1 × 10(−2) cm(2) V(−1) s(−1) in organic thin film transistors (OTFTs) as a p-channel material. As a donor in organic photovoltaics (OPVs), power conversion efficiencies (PCEs) of up to 2.18% were achieved, which is the first example of using an azine-based polymer for OPVs. These preliminary results demonstrate the potential of bithiophene-azine polymers as a new type of low-cost semiconductor material for OPVs and other organic electronics.
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spelling pubmed-90513132022-04-29 Facile synthesis of a semiconducting bithiophene-azine polymer and its application for organic thin film transistors and organic photovoltaics Wang, Guanlin Kumar, Pankaj Zhang, Zhifang Hendsbee, Arthur D. Liu, Haitao Li, Xu Wang, Jinliang Li, Yuning RSC Adv Chemistry A new azine polymer poly(4,4′-didodecyl-2,2′-bithiophene-azine) (PDDBTA) was synthesized in only three steps. PDDBTA showed hole mobilities of up to 4.1 × 10(−2) cm(2) V(−1) s(−1) in organic thin film transistors (OTFTs) as a p-channel material. As a donor in organic photovoltaics (OPVs), power conversion efficiencies (PCEs) of up to 2.18% were achieved, which is the first example of using an azine-based polymer for OPVs. These preliminary results demonstrate the potential of bithiophene-azine polymers as a new type of low-cost semiconductor material for OPVs and other organic electronics. The Royal Society of Chemistry 2020-03-31 /pmc/articles/PMC9051313/ /pubmed/35492137 http://dx.doi.org/10.1039/d0ra01211d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Wang, Guanlin
Kumar, Pankaj
Zhang, Zhifang
Hendsbee, Arthur D.
Liu, Haitao
Li, Xu
Wang, Jinliang
Li, Yuning
Facile synthesis of a semiconducting bithiophene-azine polymer and its application for organic thin film transistors and organic photovoltaics
title Facile synthesis of a semiconducting bithiophene-azine polymer and its application for organic thin film transistors and organic photovoltaics
title_full Facile synthesis of a semiconducting bithiophene-azine polymer and its application for organic thin film transistors and organic photovoltaics
title_fullStr Facile synthesis of a semiconducting bithiophene-azine polymer and its application for organic thin film transistors and organic photovoltaics
title_full_unstemmed Facile synthesis of a semiconducting bithiophene-azine polymer and its application for organic thin film transistors and organic photovoltaics
title_short Facile synthesis of a semiconducting bithiophene-azine polymer and its application for organic thin film transistors and organic photovoltaics
title_sort facile synthesis of a semiconducting bithiophene-azine polymer and its application for organic thin film transistors and organic photovoltaics
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9051313/
https://www.ncbi.nlm.nih.gov/pubmed/35492137
http://dx.doi.org/10.1039/d0ra01211d
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