Cargando…

Small organic molecules with tailored structures: initiators in the transition-metal-free C–H arylation of unactivated arenes

Simple, small organic molecules containing nitrogen and oxygen atoms in their structures have been disclosed to catalyze transition-metal-free C–H arylation of unactivated arenes with aryl iodides in the presence of (t)BuOK. In this article, an optimized catalytically active molecule, (2-(methylamin...

Descripción completa

Detalles Bibliográficos
Autores principales:	Liu, Zhenghui, Wang, Peng, Chen, Yu, Yan, Zhenzhong, Chen, Suqing, Chen, Wenjun, Mu, Tiancheng
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9051888/ https://www.ncbi.nlm.nih.gov/pubmed/35497128 http://dx.doi.org/10.1039/d0ra01845g

Ejemplares similares

Rhodium-catalyzed reductive carbonylation of aryl iodides to arylaldehydes with syngas
por: Liu, Zhenghui, et al.
Publicado: (2020)

Transition‐Metal‐Free Coupling of Polyfluorinated Arenes and Functionalized, Masked Aryl Nucleophiles
por: Finck, Lucie, et al.
Publicado: (2021)

Formal C−H Carboxylation of Unactivated Arenes
por: Gevorgyan, Ashot, et al.
Publicado: (2020)

Transition Metal-Free 1,2-Carboboration of Unactivated Alkenes
por: Cheng, Ying, et al.
Publicado: (2018)

Asymmetric Catalytic Friedel–Crafts Reactions of Unactivated Arenes
por: Brunen, Sebastian, et al.
Publicado: (2023)

BNN-1,3-dipoles: isolation and intramolecular cycloaddition with unactivated arenes
por: Guo, Rui, et al.
Publicado: (2020)

Metal-free electrochemical dihydroxylation of unactivated alkenes
por: Liu, Min, et al.
Publicado: (2023)

NMR analysis of t‐butyl‐catalyzed deuterium exchange at unactivated arene localities
por: Stack, Douglas E., et al.
Publicado: (2016)

Catalytic intramolecular aminoarylation of unactivated alkenes with aryl sulfonamides
por: Noten, Efrey A., et al.
Publicado: (2022)

Light-induced metal-free transformations of unactivated pyridotriazoles
por: Zhang, Ziyan, et al.
Publicado: (2019)

Nickel-catalyzed asymmetric reductive aryl-allylation of unactivated alkenes
por: Lin, Zhiyang, et al.
Publicado: (2021)

Preparation of cyclic imides from alkene-tethered amides: application of homogeneous Cu(ii) catalytic systems
por: Liu, Zhenghui, et al.
Publicado: (2020)

Room temperature catalytic carbon–hydrogen bond alumination of unactivated arenes: mechanism and selectivity
por: Hooper, Thomas N., et al.
Publicado: (2018)

Selective cleavage of unactivated arene ring C–C bonds by iridium: key roles of benzylic C–H activation and metal–metal cooperativity
por: Tian, Yancong, et al.
Publicado: (2021)

Synthesis of thioethers, arenes and arylated benzoxazoles by transformation of the C(aryl)–C bond of aryl alcohols
por: Liu, Mingyang, et al.
Publicado: (2020)

Catalytic reduction of aryl trialkylammonium salts to aryl silanes and arenes
por: Rand, Alexander W., et al.
Publicado: (2019)

Direct C(sp(2))–H alkylation of unactivated arenes enabled by photoinduced Pd catalysis
por: Kim, Daeun, et al.
Publicado: (2020)

Nickel-catalyzed electrochemical carboxylation of unactivated aryl and alkyl halides with CO(2)
por: Sun, Guo-Quan, et al.
Publicado: (2021)

Metal-free visible-light-enabled vicinal trifluoromethyl dithiolation of unactivated alkenes
por: Li, Xiaojuan, et al.
Publicado: (2021)

Trifluoromethanesulfonyl azide as a bifunctional reagent for metal-free azidotrifluoromethylation of unactivated alkenes
por: Huang, Hong-Gui, et al.
Publicado: (2021)

Transition Metal- and Oxidant-Free Base-Mediated Selenation of Bicyclic Arenes at Room Temperature
por: Ghosh, Tubai, et al.
Publicado: (2018)

Metal-free alcohol-directed regioselective heteroarylation of remote unactivated C(sp(3))–H bonds
por: Wu, Xinxin, et al.
Publicado: (2018)

Tuning Reactivity and Site Selectivity of Simple Arenes in C–H Activation: Ortho-Arylation of Anisoles via Arene–Metal π-Complexation
por: Ricci, Paolo, et al.
Publicado: (2014)

Practical, metal-free remote heteroarylation of amides via unactivated C(sp(3))–H bond functionalization
por: Tang, Nana, et al.
Publicado: (2019)

Aryl-to-alkyl radical relay Heck reaction of amides with vinyl arenes
por: Du, Yu-jia, et al.
Publicado: (2023)

Boron-catalysed transition-metal-free arylation and alkenylation of allylic alcohols with boronic acids
por: Lu, Sixian, et al.
Publicado: (2023)

Transition-Metal Catalyst Free Oxidative Radical Arylation of N-Methylpyrrole
por: Kocaoğlu, Esma, et al.
Publicado: (2017)

Author Correction: Direct C(sp(2))–H alkylation of unactivated arenes enabled by photoinduced Pd catalysis
por: Kim, Daeun, et al.
Publicado: (2020)

Stereoconvergent Arylations and Alkenylations of Unactivated Alkyl Electrophiles: Catalytic Enantioselective Synthesis of Secondary Sulfonamides and Sulfones
por: Choi, Junwon, et al.
Publicado: (2014)

Nickel(0)-catalyzed linear-selective hydroarylation of unactivated alkenes and styrenes with aryl boronic acids
por: Lv, Honggui, et al.
Publicado: (2018)

A general metal-free approach for the stereoselective synthesis of C-glycals from unactivated alkynes
por: Devari, Shekaraiah, et al.
Publicado: (2014)

Transition Metal‐Free N‐Arylation of Amino Acid Esters with Diaryliodonium Salts
por: Kervefors, Gabriella, et al.
Publicado: (2021)

Transition-metal-free synthesis of aryl 1-thioglycosides with arynes at room temperature
por: Liu, Yao, et al.
Publicado: (2021)

Metal-free C–H arylation of imidazoheterocycles with aryl hydrazines
por: Jana, Sourav, et al.
Publicado: (2018)

Dual gold and photoredox catalysed C–H activation of arenes for aryl–aryl cross couplings
por: Gauchot, V., et al.
Publicado: (2017)

Improving the sustainability of the ruthenium-catalysed N-directed C–H arylation of arenes with aryl halides
por: Findlay, Michael T., et al.
Publicado: (2023)

Aqueous Synthesis of 1-H-2-Substituted Benzimidazoles via Transition-Metal-Free Intramolecular Amination of Aryl Iodides
por: Chen, Chunxia, et al.
Publicado: (2012)

Expanding chemical space by para-C−H arylation of arenes
por: Maiti, Sudip, et al.
Publicado: (2022)

Ni(ii)-catalyzed mono-selective ortho-arylation of unactivated aryl C–H bonds utilizing amino acids as a directing group
por: Cong, Zhanqing, et al.
Publicado: (2019)

Solvent- and transition metal-free amide synthesis from phenyl esters and aryl amines
por: Rzhevskiy, Sergey A., et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_bvbjq8a1nk8ntvbjsihnq2qjes