The curious case of salicylidene-based fluoride sensors: chemosensors or chemodosimeters or none of them

Fluoride-ion induced hydrolysis of imine (C[double bond, length as m-dash]N) bonds has not been documented in the literature, in spite of the numerous salicylidene-based fluoride sensors studied over the years. Herein, we have proposed a mechanism for fluoride-ion induced hydrolysis of salicylidene...

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Detalles Bibliográficos
Autores principales: Dey, Sandeep Kumar, Janiak, Christoph
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9052090/
https://www.ncbi.nlm.nih.gov/pubmed/35497153
http://dx.doi.org/10.1039/d0ra02293d
Descripción
Sumario:Fluoride-ion induced hydrolysis of imine (C[double bond, length as m-dash]N) bonds has not been documented in the literature, in spite of the numerous salicylidene-based fluoride sensors studied over the years. Herein, we have proposed a mechanism for fluoride-ion induced hydrolysis of salicylidene compounds (SL and CL1–3) based on (1)H-NMR, (19)F-NMR, LC-MS and UV-vis spectroscopy experiments.

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