Cargando…

The curious case of salicylidene-based fluoride sensors: chemosensors or chemodosimeters or none of them

Fluoride-ion induced hydrolysis of imine (C[double bond, length as m-dash]N) bonds has not been documented in the literature, in spite of the numerous salicylidene-based fluoride sensors studied over the years. Herein, we have proposed a mechanism for fluoride-ion induced hydrolysis of salicylidene...

Descripción completa

Detalles Bibliográficos
Autores principales: Dey, Sandeep Kumar, Janiak, Christoph
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9052090/
https://www.ncbi.nlm.nih.gov/pubmed/35497153
http://dx.doi.org/10.1039/d0ra02293d
_version_ 1784696711467237376
author Dey, Sandeep Kumar
Janiak, Christoph
author_facet Dey, Sandeep Kumar
Janiak, Christoph
author_sort Dey, Sandeep Kumar
collection PubMed
description Fluoride-ion induced hydrolysis of imine (C[double bond, length as m-dash]N) bonds has not been documented in the literature, in spite of the numerous salicylidene-based fluoride sensors studied over the years. Herein, we have proposed a mechanism for fluoride-ion induced hydrolysis of salicylidene compounds (SL and CL1–3) based on (1)H-NMR, (19)F-NMR, LC-MS and UV-vis spectroscopy experiments.
format Online
Article
Text
id pubmed-9052090
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-90520902022-04-29 The curious case of salicylidene-based fluoride sensors: chemosensors or chemodosimeters or none of them Dey, Sandeep Kumar Janiak, Christoph RSC Adv Chemistry Fluoride-ion induced hydrolysis of imine (C[double bond, length as m-dash]N) bonds has not been documented in the literature, in spite of the numerous salicylidene-based fluoride sensors studied over the years. Herein, we have proposed a mechanism for fluoride-ion induced hydrolysis of salicylidene compounds (SL and CL1–3) based on (1)H-NMR, (19)F-NMR, LC-MS and UV-vis spectroscopy experiments. The Royal Society of Chemistry 2020-04-14 /pmc/articles/PMC9052090/ /pubmed/35497153 http://dx.doi.org/10.1039/d0ra02293d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Dey, Sandeep Kumar
Janiak, Christoph
The curious case of salicylidene-based fluoride sensors: chemosensors or chemodosimeters or none of them
title The curious case of salicylidene-based fluoride sensors: chemosensors or chemodosimeters or none of them
title_full The curious case of salicylidene-based fluoride sensors: chemosensors or chemodosimeters or none of them
title_fullStr The curious case of salicylidene-based fluoride sensors: chemosensors or chemodosimeters or none of them
title_full_unstemmed The curious case of salicylidene-based fluoride sensors: chemosensors or chemodosimeters or none of them
title_short The curious case of salicylidene-based fluoride sensors: chemosensors or chemodosimeters or none of them
title_sort curious case of salicylidene-based fluoride sensors: chemosensors or chemodosimeters or none of them
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9052090/
https://www.ncbi.nlm.nih.gov/pubmed/35497153
http://dx.doi.org/10.1039/d0ra02293d
work_keys_str_mv AT deysandeepkumar thecuriouscaseofsalicylidenebasedfluoridesensorschemosensorsorchemodosimetersornoneofthem
AT janiakchristoph thecuriouscaseofsalicylidenebasedfluoridesensorschemosensorsorchemodosimetersornoneofthem
AT deysandeepkumar curiouscaseofsalicylidenebasedfluoridesensorschemosensorsorchemodosimetersornoneofthem
AT janiakchristoph curiouscaseofsalicylidenebasedfluoridesensorschemosensorsorchemodosimetersornoneofthem