A new class of organoplatinum-based DFNS for the production of cyclic carbonates from olefins and CO(2)

We studied the potential application of an efficient, reusable, and easily recoverable catalyst of dendritic fibrous nanosilica (DFNS)-supported platinum(ii) complexes (DFNS/Pt(ii) NPs) to form cyclic carbonates in the presence of epoxides by converting carbon dioxide. Cyclic carbonates from epoxide...

Descripción completa

Detalles Bibliográficos
Autores principales: Abassian, Maryam, Zhiani, Rahele, Motavalizadehkakhky, Alireza, Eshghi, Hossein, Mehrzad, Jamshid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9052291/
https://www.ncbi.nlm.nih.gov/pubmed/35495475
http://dx.doi.org/10.1039/d0ra01696a
Descripción
Sumario:We studied the potential application of an efficient, reusable, and easily recoverable catalyst of dendritic fibrous nanosilica (DFNS)-supported platinum(ii) complexes (DFNS/Pt(ii) NPs) to form cyclic carbonates in the presence of epoxides by converting carbon dioxide. Cyclic carbonates from epoxides and carbon dioxide is proposed as the most appropriate way to synthesis this C1 building block. We performed FE-SEM, TEM, TGA, BET, VSM, and ICP-MS to thoroughly characterize DFNS/Pt(ii) NPs.

Ejemplares similares