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A new class of organoplatinum-based DFNS for the production of cyclic carbonates from olefins and CO(2)
We studied the potential application of an efficient, reusable, and easily recoverable catalyst of dendritic fibrous nanosilica (DFNS)-supported platinum(ii) complexes (DFNS/Pt(ii) NPs) to form cyclic carbonates in the presence of epoxides by converting carbon dioxide. Cyclic carbonates from epoxide...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9052291/ https://www.ncbi.nlm.nih.gov/pubmed/35495475 http://dx.doi.org/10.1039/d0ra01696a |
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author | Abassian, Maryam Zhiani, Rahele Motavalizadehkakhky, Alireza Eshghi, Hossein Mehrzad, Jamshid |
author_facet | Abassian, Maryam Zhiani, Rahele Motavalizadehkakhky, Alireza Eshghi, Hossein Mehrzad, Jamshid |
author_sort | Abassian, Maryam |
collection | PubMed |
description | We studied the potential application of an efficient, reusable, and easily recoverable catalyst of dendritic fibrous nanosilica (DFNS)-supported platinum(ii) complexes (DFNS/Pt(ii) NPs) to form cyclic carbonates in the presence of epoxides by converting carbon dioxide. Cyclic carbonates from epoxides and carbon dioxide is proposed as the most appropriate way to synthesis this C1 building block. We performed FE-SEM, TEM, TGA, BET, VSM, and ICP-MS to thoroughly characterize DFNS/Pt(ii) NPs. |
format | Online Article Text |
id | pubmed-9052291 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90522912022-04-29 A new class of organoplatinum-based DFNS for the production of cyclic carbonates from olefins and CO(2) Abassian, Maryam Zhiani, Rahele Motavalizadehkakhky, Alireza Eshghi, Hossein Mehrzad, Jamshid RSC Adv Chemistry We studied the potential application of an efficient, reusable, and easily recoverable catalyst of dendritic fibrous nanosilica (DFNS)-supported platinum(ii) complexes (DFNS/Pt(ii) NPs) to form cyclic carbonates in the presence of epoxides by converting carbon dioxide. Cyclic carbonates from epoxides and carbon dioxide is proposed as the most appropriate way to synthesis this C1 building block. We performed FE-SEM, TEM, TGA, BET, VSM, and ICP-MS to thoroughly characterize DFNS/Pt(ii) NPs. The Royal Society of Chemistry 2020-04-16 /pmc/articles/PMC9052291/ /pubmed/35495475 http://dx.doi.org/10.1039/d0ra01696a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Abassian, Maryam Zhiani, Rahele Motavalizadehkakhky, Alireza Eshghi, Hossein Mehrzad, Jamshid A new class of organoplatinum-based DFNS for the production of cyclic carbonates from olefins and CO(2) |
title | A new class of organoplatinum-based DFNS for the production of cyclic carbonates from olefins and CO(2) |
title_full | A new class of organoplatinum-based DFNS for the production of cyclic carbonates from olefins and CO(2) |
title_fullStr | A new class of organoplatinum-based DFNS for the production of cyclic carbonates from olefins and CO(2) |
title_full_unstemmed | A new class of organoplatinum-based DFNS for the production of cyclic carbonates from olefins and CO(2) |
title_short | A new class of organoplatinum-based DFNS for the production of cyclic carbonates from olefins and CO(2) |
title_sort | new class of organoplatinum-based dfns for the production of cyclic carbonates from olefins and co(2) |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9052291/ https://www.ncbi.nlm.nih.gov/pubmed/35495475 http://dx.doi.org/10.1039/d0ra01696a |
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