Operando Observation of Oxygenated Intermediates during CO Hydrogenation on Rh Single Crystals

[Image: see text] The CO hydrogenation reaction over the Rh(111) and (211) surfaces has been investigated operando by X-ray photoelectron spectroscopy at a pressure of 150 mbar. Observations of the resting state of the catalyst give mechanistic insight into the selectivity of Rh for generating ethan...

Descripción completa

Detalles Bibliográficos
Autores principales: Degerman, David, Shipilin, Mikhail, Lömker, Patrick, Goodwin, Christopher M., Gericke, Sabrina M., Hejral, Uta, Gladh, Jörgen, Wang, Hsin-Yi, Schlueter, Christoph, Nilsson, Anders, Amann, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9052753/
https://www.ncbi.nlm.nih.gov/pubmed/35394273
http://dx.doi.org/10.1021/jacs.2c00300
_version_ 1784696850142461952
author Degerman, David
Shipilin, Mikhail
Lömker, Patrick
Goodwin, Christopher M.
Gericke, Sabrina M.
Hejral, Uta
Gladh, Jörgen
Wang, Hsin-Yi
Schlueter, Christoph
Nilsson, Anders
Amann, Peter
author_facet Degerman, David
Shipilin, Mikhail
Lömker, Patrick
Goodwin, Christopher M.
Gericke, Sabrina M.
Hejral, Uta
Gladh, Jörgen
Wang, Hsin-Yi
Schlueter, Christoph
Nilsson, Anders
Amann, Peter
author_sort Degerman, David
collection PubMed
description [Image: see text] The CO hydrogenation reaction over the Rh(111) and (211) surfaces has been investigated operando by X-ray photoelectron spectroscopy at a pressure of 150 mbar. Observations of the resting state of the catalyst give mechanistic insight into the selectivity of Rh for generating ethanol from CO hydrogenation. This study shows that the Rh(111) surface does not dissociate all CO molecules before hydrogenation of the O and C atoms, which allows methoxy and other both oxygenated and hydrogenated species to be visible in the photoelectron spectra.
format Online
Article
Text
id pubmed-9052753
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-90527532022-05-02 Operando Observation of Oxygenated Intermediates during CO Hydrogenation on Rh Single Crystals Degerman, David Shipilin, Mikhail Lömker, Patrick Goodwin, Christopher M. Gericke, Sabrina M. Hejral, Uta Gladh, Jörgen Wang, Hsin-Yi Schlueter, Christoph Nilsson, Anders Amann, Peter J Am Chem Soc [Image: see text] The CO hydrogenation reaction over the Rh(111) and (211) surfaces has been investigated operando by X-ray photoelectron spectroscopy at a pressure of 150 mbar. Observations of the resting state of the catalyst give mechanistic insight into the selectivity of Rh for generating ethanol from CO hydrogenation. This study shows that the Rh(111) surface does not dissociate all CO molecules before hydrogenation of the O and C atoms, which allows methoxy and other both oxygenated and hydrogenated species to be visible in the photoelectron spectra. American Chemical Society 2022-04-08 2022-04-27 /pmc/articles/PMC9052753/ /pubmed/35394273 http://dx.doi.org/10.1021/jacs.2c00300 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Degerman, David
Shipilin, Mikhail
Lömker, Patrick
Goodwin, Christopher M.
Gericke, Sabrina M.
Hejral, Uta
Gladh, Jörgen
Wang, Hsin-Yi
Schlueter, Christoph
Nilsson, Anders
Amann, Peter
Operando Observation of Oxygenated Intermediates during CO Hydrogenation on Rh Single Crystals
title Operando Observation of Oxygenated Intermediates during CO Hydrogenation on Rh Single Crystals
title_full Operando Observation of Oxygenated Intermediates during CO Hydrogenation on Rh Single Crystals
title_fullStr Operando Observation of Oxygenated Intermediates during CO Hydrogenation on Rh Single Crystals
title_full_unstemmed Operando Observation of Oxygenated Intermediates during CO Hydrogenation on Rh Single Crystals
title_short Operando Observation of Oxygenated Intermediates during CO Hydrogenation on Rh Single Crystals
title_sort operando observation of oxygenated intermediates during co hydrogenation on rh single crystals
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9052753/
https://www.ncbi.nlm.nih.gov/pubmed/35394273
http://dx.doi.org/10.1021/jacs.2c00300
work_keys_str_mv AT degermandavid operandoobservationofoxygenatedintermediatesduringcohydrogenationonrhsinglecrystals
AT shipilinmikhail operandoobservationofoxygenatedintermediatesduringcohydrogenationonrhsinglecrystals
AT lomkerpatrick operandoobservationofoxygenatedintermediatesduringcohydrogenationonrhsinglecrystals
AT goodwinchristopherm operandoobservationofoxygenatedintermediatesduringcohydrogenationonrhsinglecrystals
AT gerickesabrinam operandoobservationofoxygenatedintermediatesduringcohydrogenationonrhsinglecrystals
AT hejraluta operandoobservationofoxygenatedintermediatesduringcohydrogenationonrhsinglecrystals
AT gladhjorgen operandoobservationofoxygenatedintermediatesduringcohydrogenationonrhsinglecrystals
AT wanghsinyi operandoobservationofoxygenatedintermediatesduringcohydrogenationonrhsinglecrystals
AT schlueterchristoph operandoobservationofoxygenatedintermediatesduringcohydrogenationonrhsinglecrystals
AT nilssonanders operandoobservationofoxygenatedintermediatesduringcohydrogenationonrhsinglecrystals
AT amannpeter operandoobservationofoxygenatedintermediatesduringcohydrogenationonrhsinglecrystals

Ejemplares similares