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Concerted and Stepwise Proton-Coupled Electron Transfer for Tryptophan-Derivative Oxidation with Water as the Primary Proton Acceptor: Clarifying a Controversy

[Image: see text] Concerted electron-proton transfer (CEPT) reactions avoid charged intermediates and may be energetically favorable for redox and radical-transfer reactions in natural and synthetic systems. Tryptophan (W) often partakes in radical-transfer chains in nature but has been proposed to...

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Detalles Bibliográficos
Autores principales:	Nilsen-Moe, Astrid, Rosichini, Andrea, Glover, Starla D., Hammarström, Leif
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9052761/ https://www.ncbi.nlm.nih.gov/pubmed/35416654 http://dx.doi.org/10.1021/jacs.2c00371

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