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Effect of temperature and large guest molecules on the C–H symmetric stretching vibrational frequencies of methane in structure H and I clathrate hydrates
Large molecules such as 2-methylbutane (C(5)H(12)) or 2,2-dimethylbutane (C(6)H(14)) form structure H (sH) hydrates with methane (CH(4)) as a help gas. In this study, the Raman spectra of the C–H symmetric stretch region of CH(4) enclathrated within various sH hydrates and structure I CH(4) hydrates...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9053386/ https://www.ncbi.nlm.nih.gov/pubmed/35515622 http://dx.doi.org/10.1039/d0ra02748k |
Sumario: | Large molecules such as 2-methylbutane (C(5)H(12)) or 2,2-dimethylbutane (C(6)H(14)) form structure H (sH) hydrates with methane (CH(4)) as a help gas. In this study, the Raman spectra of the C–H symmetric stretch region of CH(4) enclathrated within various sH hydrates and structure I CH(4) hydrates were analyzed in the temperature range 137.7–205.4 K. Thermal expansions of these sH hydrate samples were also measured using powder X-ray diffraction. Symmetric stretch vibrational frequencies of CH(4) in host–water cages increased because of varying temperature, and the sizes of the host–water cages also increased; variation of CH(4) in small cages was less than in larger cages. Comparing the variations of the C–H symmetric stretching frequencies of CH(4) in gas hydrates with varying pressure and temperature, we suggest that the observed trend is caused by thermal vibrations of the CH(4) molecule in water cages. |
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