SO(2)F(2)-Mediated one-pot cascade process for transformation of aldehydes (RCHO) to cyanamides (RNHCN)

A simple, mild and practical cascade process for the direct conversion of aldehydes to cyanamides was developed featuring a wide substrate scope and great functional group tolerability. This method allows for transformations of readily available, inexpensive, and abundant aldehydes to highly valuabl...

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Detalles Bibliográficos
Autores principales: Zhao, Yiyong, Wei, Junjie, Ge, Shuting, Zhang, Guofu, Ding, Chengrong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9053412/
https://www.ncbi.nlm.nih.gov/pubmed/35521444
http://dx.doi.org/10.1039/d0ra02631j
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author Zhao, Yiyong
Wei, Junjie
Ge, Shuting
Zhang, Guofu
Ding, Chengrong
author_facet Zhao, Yiyong
Wei, Junjie
Ge, Shuting
Zhang, Guofu
Ding, Chengrong
author_sort Zhao, Yiyong
collection PubMed
description A simple, mild and practical cascade process for the direct conversion of aldehydes to cyanamides was developed featuring a wide substrate scope and great functional group tolerability. This method allows for transformations of readily available, inexpensive, and abundant aldehydes to highly valuable cyanamides in a pot, atom, and step-economical manner with a green nitrogen source. This protocol will serve as a robust tool for the installation of the cyanamide moiety in various complicated molecules.
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spelling pubmed-90534122022-05-04 SO(2)F(2)-Mediated one-pot cascade process for transformation of aldehydes (RCHO) to cyanamides (RNHCN) Zhao, Yiyong Wei, Junjie Ge, Shuting Zhang, Guofu Ding, Chengrong RSC Adv Chemistry A simple, mild and practical cascade process for the direct conversion of aldehydes to cyanamides was developed featuring a wide substrate scope and great functional group tolerability. This method allows for transformations of readily available, inexpensive, and abundant aldehydes to highly valuable cyanamides in a pot, atom, and step-economical manner with a green nitrogen source. This protocol will serve as a robust tool for the installation of the cyanamide moiety in various complicated molecules. The Royal Society of Chemistry 2020-05-04 /pmc/articles/PMC9053412/ /pubmed/35521444 http://dx.doi.org/10.1039/d0ra02631j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Zhao, Yiyong
Wei, Junjie
Ge, Shuting
Zhang, Guofu
Ding, Chengrong
SO(2)F(2)-Mediated one-pot cascade process for transformation of aldehydes (RCHO) to cyanamides (RNHCN)
title SO(2)F(2)-Mediated one-pot cascade process for transformation of aldehydes (RCHO) to cyanamides (RNHCN)
title_full SO(2)F(2)-Mediated one-pot cascade process for transformation of aldehydes (RCHO) to cyanamides (RNHCN)
title_fullStr SO(2)F(2)-Mediated one-pot cascade process for transformation of aldehydes (RCHO) to cyanamides (RNHCN)
title_full_unstemmed SO(2)F(2)-Mediated one-pot cascade process for transformation of aldehydes (RCHO) to cyanamides (RNHCN)
title_short SO(2)F(2)-Mediated one-pot cascade process for transformation of aldehydes (RCHO) to cyanamides (RNHCN)
title_sort so(2)f(2)-mediated one-pot cascade process for transformation of aldehydes (rcho) to cyanamides (rnhcn)
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9053412/
https://www.ncbi.nlm.nih.gov/pubmed/35521444
http://dx.doi.org/10.1039/d0ra02631j
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