Chlorotrifluoroethylidenes: an efficient and convenient approach to their synthesis

A convenient one step synthesis of chlorotrifluoroalkyl olefins starting from aldehydes was developed. The stable reagent 2-((1-chloro-2,2,2-trifluoroethyl)sulfonyl)benzothiazole was prepared from readily available benzothiazole-2-thiol and halothane. This method comprises using stable 2-((1-chloro-...

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Autores principales: Upare, Abhay Atmaram, Gadekar, Pradip K., Jadhav, Kiran, Sivaramakrishnan, H., Roopan, Selvaraj Mohana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9053503/
https://www.ncbi.nlm.nih.gov/pubmed/35515602
http://dx.doi.org/10.1039/d0ra02481c
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author Upare, Abhay Atmaram
Gadekar, Pradip K.
Jadhav, Kiran
Sivaramakrishnan, H.
Roopan, Selvaraj Mohana
author_facet Upare, Abhay Atmaram
Gadekar, Pradip K.
Jadhav, Kiran
Sivaramakrishnan, H.
Roopan, Selvaraj Mohana
author_sort Upare, Abhay Atmaram
collection PubMed
description A convenient one step synthesis of chlorotrifluoroalkyl olefins starting from aldehydes was developed. The stable reagent 2-((1-chloro-2,2,2-trifluoroethyl)sulfonyl)benzothiazole was prepared from readily available benzothiazole-2-thiol and halothane. This method comprises using stable 2-((1-chloro-2,2,2-trifluoroethyl)sulfonyl)benzothiazole according to the Julia procedure and presents new opportunities for the synthesis of trifluoroalkylidene derivatives.
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spelling pubmed-90535032022-05-04 Chlorotrifluoroethylidenes: an efficient and convenient approach to their synthesis Upare, Abhay Atmaram Gadekar, Pradip K. Jadhav, Kiran Sivaramakrishnan, H. Roopan, Selvaraj Mohana RSC Adv Chemistry A convenient one step synthesis of chlorotrifluoroalkyl olefins starting from aldehydes was developed. The stable reagent 2-((1-chloro-2,2,2-trifluoroethyl)sulfonyl)benzothiazole was prepared from readily available benzothiazole-2-thiol and halothane. This method comprises using stable 2-((1-chloro-2,2,2-trifluoroethyl)sulfonyl)benzothiazole according to the Julia procedure and presents new opportunities for the synthesis of trifluoroalkylidene derivatives. The Royal Society of Chemistry 2020-05-05 /pmc/articles/PMC9053503/ /pubmed/35515602 http://dx.doi.org/10.1039/d0ra02481c Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Upare, Abhay Atmaram
Gadekar, Pradip K.
Jadhav, Kiran
Sivaramakrishnan, H.
Roopan, Selvaraj Mohana
Chlorotrifluoroethylidenes: an efficient and convenient approach to their synthesis
title Chlorotrifluoroethylidenes: an efficient and convenient approach to their synthesis
title_full Chlorotrifluoroethylidenes: an efficient and convenient approach to their synthesis
title_fullStr Chlorotrifluoroethylidenes: an efficient and convenient approach to their synthesis
title_full_unstemmed Chlorotrifluoroethylidenes: an efficient and convenient approach to their synthesis
title_short Chlorotrifluoroethylidenes: an efficient and convenient approach to their synthesis
title_sort chlorotrifluoroethylidenes: an efficient and convenient approach to their synthesis
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9053503/
https://www.ncbi.nlm.nih.gov/pubmed/35515602
http://dx.doi.org/10.1039/d0ra02481c
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