Borohydride catalyzed redistribution reaction of hydrosilane and chlorosilane: a potential system for facile preparation of hydrochlorosilanes

Various borohydrides were found to catalyze the redistribution reaction of hydrosilane and chlorosilane in different solvents to produce hydrochlorosilanes efficiently and facilely. The redistribution reaction was affected by solvent and catalyst. The substrate scope was investigated in HMPA with Li...

Descripción completa

Detalles Bibliográficos
Autores principales: Chen, Yi, Ai, Liqing, Li, Yongming, Xu, Caihong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9053603/
https://www.ncbi.nlm.nih.gov/pubmed/35515620
http://dx.doi.org/10.1039/d0ra03536j
_version_ 1784697016672059392
author Chen, Yi
Ai, Liqing
Li, Yongming
Xu, Caihong
author_facet Chen, Yi
Ai, Liqing
Li, Yongming
Xu, Caihong
author_sort Chen, Yi
collection PubMed
description Various borohydrides were found to catalyze the redistribution reaction of hydrosilane and chlorosilane in different solvents to produce hydrochlorosilanes efficiently and facilely. The redistribution reaction was affected by solvent and catalyst. The substrate scope was investigated in HMPA with LiBH(4) as catalyst. A possible mechanism was proposed to explain the redistribution process.
format Online
Article
Text
id pubmed-9053603
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-90536032022-05-04 Borohydride catalyzed redistribution reaction of hydrosilane and chlorosilane: a potential system for facile preparation of hydrochlorosilanes Chen, Yi Ai, Liqing Li, Yongming Xu, Caihong RSC Adv Chemistry Various borohydrides were found to catalyze the redistribution reaction of hydrosilane and chlorosilane in different solvents to produce hydrochlorosilanes efficiently and facilely. The redistribution reaction was affected by solvent and catalyst. The substrate scope was investigated in HMPA with LiBH(4) as catalyst. A possible mechanism was proposed to explain the redistribution process. The Royal Society of Chemistry 2020-05-05 /pmc/articles/PMC9053603/ /pubmed/35515620 http://dx.doi.org/10.1039/d0ra03536j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Chen, Yi
Ai, Liqing
Li, Yongming
Xu, Caihong
Borohydride catalyzed redistribution reaction of hydrosilane and chlorosilane: a potential system for facile preparation of hydrochlorosilanes
title Borohydride catalyzed redistribution reaction of hydrosilane and chlorosilane: a potential system for facile preparation of hydrochlorosilanes
title_full Borohydride catalyzed redistribution reaction of hydrosilane and chlorosilane: a potential system for facile preparation of hydrochlorosilanes
title_fullStr Borohydride catalyzed redistribution reaction of hydrosilane and chlorosilane: a potential system for facile preparation of hydrochlorosilanes
title_full_unstemmed Borohydride catalyzed redistribution reaction of hydrosilane and chlorosilane: a potential system for facile preparation of hydrochlorosilanes
title_short Borohydride catalyzed redistribution reaction of hydrosilane and chlorosilane: a potential system for facile preparation of hydrochlorosilanes
title_sort borohydride catalyzed redistribution reaction of hydrosilane and chlorosilane: a potential system for facile preparation of hydrochlorosilanes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9053603/
https://www.ncbi.nlm.nih.gov/pubmed/35515620
http://dx.doi.org/10.1039/d0ra03536j
work_keys_str_mv AT chenyi borohydridecatalyzedredistributionreactionofhydrosilaneandchlorosilaneapotentialsystemforfacilepreparationofhydrochlorosilanes
AT ailiqing borohydridecatalyzedredistributionreactionofhydrosilaneandchlorosilaneapotentialsystemforfacilepreparationofhydrochlorosilanes
AT liyongming borohydridecatalyzedredistributionreactionofhydrosilaneandchlorosilaneapotentialsystemforfacilepreparationofhydrochlorosilanes
AT xucaihong borohydridecatalyzedredistributionreactionofhydrosilaneandchlorosilaneapotentialsystemforfacilepreparationofhydrochlorosilanes

Ejemplares similares