Emodin as a novel organic photocatalyst for selective oxidation of sulfides under mild conditions

Herein, we have developed naturally-occurring Emodin, which is commercially available at low-cost, as a novel organic photocatalyst for the first time. Emodin was successfully employed in the selective oxidation of sulfides promoted by visible-light, delivering valuable sulfoxides with high efficien...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Yan, Lou, Jiangli, Li, Min, Yuan, Zhenbo, Rao, Yijian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054162/
https://www.ncbi.nlm.nih.gov/pubmed/35520433
http://dx.doi.org/10.1039/d0ra02702b
_version_ 1784697134659928064
author Zhang, Yan
Lou, Jiangli
Li, Min
Yuan, Zhenbo
Rao, Yijian
author_facet Zhang, Yan
Lou, Jiangli
Li, Min
Yuan, Zhenbo
Rao, Yijian
author_sort Zhang, Yan
collection PubMed
description Herein, we have developed naturally-occurring Emodin, which is commercially available at low-cost, as a novel organic photocatalyst for the first time. Emodin was successfully employed in the selective oxidation of sulfides promoted by visible-light, delivering valuable sulfoxides with high efficiency. Mechanistic investigations suggested both single-electron transfer (SET) and energy transfer (EnT) pathways might be involved in the oxidation reaction.
format Online
Article
Text
id pubmed-9054162
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-90541622022-05-04 Emodin as a novel organic photocatalyst for selective oxidation of sulfides under mild conditions Zhang, Yan Lou, Jiangli Li, Min Yuan, Zhenbo Rao, Yijian RSC Adv Chemistry Herein, we have developed naturally-occurring Emodin, which is commercially available at low-cost, as a novel organic photocatalyst for the first time. Emodin was successfully employed in the selective oxidation of sulfides promoted by visible-light, delivering valuable sulfoxides with high efficiency. Mechanistic investigations suggested both single-electron transfer (SET) and energy transfer (EnT) pathways might be involved in the oxidation reaction. The Royal Society of Chemistry 2020-05-27 /pmc/articles/PMC9054162/ /pubmed/35520433 http://dx.doi.org/10.1039/d0ra02702b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Zhang, Yan
Lou, Jiangli
Li, Min
Yuan, Zhenbo
Rao, Yijian
Emodin as a novel organic photocatalyst for selective oxidation of sulfides under mild conditions
title Emodin as a novel organic photocatalyst for selective oxidation of sulfides under mild conditions
title_full Emodin as a novel organic photocatalyst for selective oxidation of sulfides under mild conditions
title_fullStr Emodin as a novel organic photocatalyst for selective oxidation of sulfides under mild conditions
title_full_unstemmed Emodin as a novel organic photocatalyst for selective oxidation of sulfides under mild conditions
title_short Emodin as a novel organic photocatalyst for selective oxidation of sulfides under mild conditions
title_sort emodin as a novel organic photocatalyst for selective oxidation of sulfides under mild conditions
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054162/
https://www.ncbi.nlm.nih.gov/pubmed/35520433
http://dx.doi.org/10.1039/d0ra02702b
work_keys_str_mv AT zhangyan emodinasanovelorganicphotocatalystforselectiveoxidationofsulfidesundermildconditions
AT loujiangli emodinasanovelorganicphotocatalystforselectiveoxidationofsulfidesundermildconditions
AT limin emodinasanovelorganicphotocatalystforselectiveoxidationofsulfidesundermildconditions
AT yuanzhenbo emodinasanovelorganicphotocatalystforselectiveoxidationofsulfidesundermildconditions
AT raoyijian emodinasanovelorganicphotocatalystforselectiveoxidationofsulfidesundermildconditions

Ejemplares similares