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Sc(3)N@I(h)-C(80) based donor–acceptor conjugate: role of thiophene spacer in promoting ultrafast excited state charge separation

Light induced charge separation in a newly synthesized triphenylamine–thiophene-Sc(3)N@I(h)-C(80) donor–acceptor conjugate and its C(60) analog, triphenylamine–thiophene-C(60) conjugate is reported, and the significance of the thiophene spacer in promoting electron transfer events is unraveled....

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Autores principales: Caballero, Rubén, Servián, Luis David, Gobeze, Habtom B., Fernandez-Delgado, Olivia, Echegoyen, Luis, D'Souza, Francis, Langa, Fernando
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054176/
https://www.ncbi.nlm.nih.gov/pubmed/35520425
http://dx.doi.org/10.1039/d0ra04379f
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author Caballero, Rubén
Servián, Luis David
Gobeze, Habtom B.
Fernandez-Delgado, Olivia
Echegoyen, Luis
D'Souza, Francis
Langa, Fernando
author_facet Caballero, Rubén
Servián, Luis David
Gobeze, Habtom B.
Fernandez-Delgado, Olivia
Echegoyen, Luis
D'Souza, Francis
Langa, Fernando
author_sort Caballero, Rubén
collection PubMed
description Light induced charge separation in a newly synthesized triphenylamine–thiophene-Sc(3)N@I(h)-C(80) donor–acceptor conjugate and its C(60) analog, triphenylamine–thiophene-C(60) conjugate is reported, and the significance of the thiophene spacer in promoting electron transfer events is unraveled.
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spelling pubmed-90541762022-05-04 Sc(3)N@I(h)-C(80) based donor–acceptor conjugate: role of thiophene spacer in promoting ultrafast excited state charge separation Caballero, Rubén Servián, Luis David Gobeze, Habtom B. Fernandez-Delgado, Olivia Echegoyen, Luis D'Souza, Francis Langa, Fernando RSC Adv Chemistry Light induced charge separation in a newly synthesized triphenylamine–thiophene-Sc(3)N@I(h)-C(80) donor–acceptor conjugate and its C(60) analog, triphenylamine–thiophene-C(60) conjugate is reported, and the significance of the thiophene spacer in promoting electron transfer events is unraveled. The Royal Society of Chemistry 2020-05-27 /pmc/articles/PMC9054176/ /pubmed/35520425 http://dx.doi.org/10.1039/d0ra04379f Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Caballero, Rubén
Servián, Luis David
Gobeze, Habtom B.
Fernandez-Delgado, Olivia
Echegoyen, Luis
D'Souza, Francis
Langa, Fernando
Sc(3)N@I(h)-C(80) based donor–acceptor conjugate: role of thiophene spacer in promoting ultrafast excited state charge separation
title Sc(3)N@I(h)-C(80) based donor–acceptor conjugate: role of thiophene spacer in promoting ultrafast excited state charge separation
title_full Sc(3)N@I(h)-C(80) based donor–acceptor conjugate: role of thiophene spacer in promoting ultrafast excited state charge separation
title_fullStr Sc(3)N@I(h)-C(80) based donor–acceptor conjugate: role of thiophene spacer in promoting ultrafast excited state charge separation
title_full_unstemmed Sc(3)N@I(h)-C(80) based donor–acceptor conjugate: role of thiophene spacer in promoting ultrafast excited state charge separation
title_short Sc(3)N@I(h)-C(80) based donor–acceptor conjugate: role of thiophene spacer in promoting ultrafast excited state charge separation
title_sort sc(3)n@i(h)-c(80) based donor–acceptor conjugate: role of thiophene spacer in promoting ultrafast excited state charge separation
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054176/
https://www.ncbi.nlm.nih.gov/pubmed/35520425
http://dx.doi.org/10.1039/d0ra04379f
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