Ionic liquids of superior thermal stability. Validation of PPh(4)(+) as an organic cation of impressive thermodynamic durability

Recent work by Wasserscheid, et al. suggests that PPh(4)(+) is an organic molecular ion of truly exceptional thermal stability. Herein we provide data that cements that conclusion: specifically, we show that aliphatic moieties of modified PPh(4)(+)-based cations incorporating methyl, methylene, or m...

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Detalles Bibliográficos
Autores principales: Soltani, Mohammad, McGeehee, Jimmie L., Stenson, Alexandra C., O'Brien, Richard A., Duranty, Edward R., Salter, E. Alan, Wierzbicki, Andrzej, Glover, T. Grant, Davis, James H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054240/
https://www.ncbi.nlm.nih.gov/pubmed/35517722
http://dx.doi.org/10.1039/d0ra03220d

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