Metal-free syntheses of new azocines via addition reactions of enaminones with acenaphthoquinone followed by oxidative cleavages of the corresponding vicinal diols

A one-pot, clean and green procedure is described for the syntheses of new azocine derivatives via addition reactions of enaminones with acenaphthoquinone followed by periodic acid-mediated oxidative cleavages of the corresponding vicinal diols. Various derivatives of azocine were prepared and well...

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Autores principales: Mousavi, S. Hekmat, Mohammadizadeh, Mohammad Reza, Arimitsu, Satoru, Saberi, Dariush, Poorsadeghi, Samira, Genta, Kojya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054298/
https://www.ncbi.nlm.nih.gov/pubmed/35517728
http://dx.doi.org/10.1039/d0ra02852e
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author Mousavi, S. Hekmat
Mohammadizadeh, Mohammad Reza
Arimitsu, Satoru
Saberi, Dariush
Poorsadeghi, Samira
Genta, Kojya
author_facet Mousavi, S. Hekmat
Mohammadizadeh, Mohammad Reza
Arimitsu, Satoru
Saberi, Dariush
Poorsadeghi, Samira
Genta, Kojya
author_sort Mousavi, S. Hekmat
collection PubMed
description A one-pot, clean and green procedure is described for the syntheses of new azocine derivatives via addition reactions of enaminones with acenaphthoquinone followed by periodic acid-mediated oxidative cleavages of the corresponding vicinal diols. Various derivatives of azocine were prepared and well characterized. The excellent yields, simple synthesis procedure, lack of a need to carry out any tedious work-up and column chromatography, metal-free catalysis, and mild reaction conditions are important features of this protocol.
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spelling pubmed-90542982022-05-04 Metal-free syntheses of new azocines via addition reactions of enaminones with acenaphthoquinone followed by oxidative cleavages of the corresponding vicinal diols Mousavi, S. Hekmat Mohammadizadeh, Mohammad Reza Arimitsu, Satoru Saberi, Dariush Poorsadeghi, Samira Genta, Kojya RSC Adv Chemistry A one-pot, clean and green procedure is described for the syntheses of new azocine derivatives via addition reactions of enaminones with acenaphthoquinone followed by periodic acid-mediated oxidative cleavages of the corresponding vicinal diols. Various derivatives of azocine were prepared and well characterized. The excellent yields, simple synthesis procedure, lack of a need to carry out any tedious work-up and column chromatography, metal-free catalysis, and mild reaction conditions are important features of this protocol. The Royal Society of Chemistry 2020-05-29 /pmc/articles/PMC9054298/ /pubmed/35517728 http://dx.doi.org/10.1039/d0ra02852e Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Mousavi, S. Hekmat
Mohammadizadeh, Mohammad Reza
Arimitsu, Satoru
Saberi, Dariush
Poorsadeghi, Samira
Genta, Kojya
Metal-free syntheses of new azocines via addition reactions of enaminones with acenaphthoquinone followed by oxidative cleavages of the corresponding vicinal diols
title Metal-free syntheses of new azocines via addition reactions of enaminones with acenaphthoquinone followed by oxidative cleavages of the corresponding vicinal diols
title_full Metal-free syntheses of new azocines via addition reactions of enaminones with acenaphthoquinone followed by oxidative cleavages of the corresponding vicinal diols
title_fullStr Metal-free syntheses of new azocines via addition reactions of enaminones with acenaphthoquinone followed by oxidative cleavages of the corresponding vicinal diols
title_full_unstemmed Metal-free syntheses of new azocines via addition reactions of enaminones with acenaphthoquinone followed by oxidative cleavages of the corresponding vicinal diols
title_short Metal-free syntheses of new azocines via addition reactions of enaminones with acenaphthoquinone followed by oxidative cleavages of the corresponding vicinal diols
title_sort metal-free syntheses of new azocines via addition reactions of enaminones with acenaphthoquinone followed by oxidative cleavages of the corresponding vicinal diols
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054298/
https://www.ncbi.nlm.nih.gov/pubmed/35517728
http://dx.doi.org/10.1039/d0ra02852e
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