FeNi(3) magnetic nanoparticles supported on ruthenium silicate-functionalized DFNS for photocatalytic CO(2) reduction to formate

For aerobic oxidation, anchoring ruthenium(ii) in the nanospaces of magnetic dendritic fibrous nanosilica (DFNS) afforded a potential nanocatalyst (the complex FeNi(3)/DFNS/Ru(ii)), which showed enhanced activity. The FeNi(3)/DFNS/Ru(ii) complex exhibited excellent catalytic activity in the reductio...

Descripción completa

Detalles Bibliográficos
Autores principales: Abeadi, Nader, Zhiani, Rahele, Motavalizadehkakhky, Alireza, Omidwar, Maryam, Hosseiny, Malihe Sadat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054344/
https://www.ncbi.nlm.nih.gov/pubmed/35517733
http://dx.doi.org/10.1039/d0ra03928d
_version_ 1784697166239891456
author Abeadi, Nader
Zhiani, Rahele
Motavalizadehkakhky, Alireza
Omidwar, Maryam
Hosseiny, Malihe Sadat
author_facet Abeadi, Nader
Zhiani, Rahele
Motavalizadehkakhky, Alireza
Omidwar, Maryam
Hosseiny, Malihe Sadat
author_sort Abeadi, Nader
collection PubMed
description For aerobic oxidation, anchoring ruthenium(ii) in the nanospaces of magnetic dendritic fibrous nanosilica (DFNS) afforded a potential nanocatalyst (the complex FeNi(3)/DFNS/Ru(ii)), which showed enhanced activity. The FeNi(3)/DFNS/Ru(ii) complex exhibited excellent catalytic activity in the reduction of carbon dioxide to formate in the presence of visible-light irradiation. We have analyzed its characteristics by using scanning electron microscopy (SEM), transmission electron microscopy (TEM), a vibrating sample magnetometer (VSM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and thermogravimetric analysis (TGA).
format Online
Article
Text
id pubmed-9054344
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-90543442022-05-04 FeNi(3) magnetic nanoparticles supported on ruthenium silicate-functionalized DFNS for photocatalytic CO(2) reduction to formate Abeadi, Nader Zhiani, Rahele Motavalizadehkakhky, Alireza Omidwar, Maryam Hosseiny, Malihe Sadat RSC Adv Chemistry For aerobic oxidation, anchoring ruthenium(ii) in the nanospaces of magnetic dendritic fibrous nanosilica (DFNS) afforded a potential nanocatalyst (the complex FeNi(3)/DFNS/Ru(ii)), which showed enhanced activity. The FeNi(3)/DFNS/Ru(ii) complex exhibited excellent catalytic activity in the reduction of carbon dioxide to formate in the presence of visible-light irradiation. We have analyzed its characteristics by using scanning electron microscopy (SEM), transmission electron microscopy (TEM), a vibrating sample magnetometer (VSM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and thermogravimetric analysis (TGA). The Royal Society of Chemistry 2020-05-29 /pmc/articles/PMC9054344/ /pubmed/35517733 http://dx.doi.org/10.1039/d0ra03928d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Abeadi, Nader
Zhiani, Rahele
Motavalizadehkakhky, Alireza
Omidwar, Maryam
Hosseiny, Malihe Sadat
FeNi(3) magnetic nanoparticles supported on ruthenium silicate-functionalized DFNS for photocatalytic CO(2) reduction to formate
title FeNi(3) magnetic nanoparticles supported on ruthenium silicate-functionalized DFNS for photocatalytic CO(2) reduction to formate
title_full FeNi(3) magnetic nanoparticles supported on ruthenium silicate-functionalized DFNS for photocatalytic CO(2) reduction to formate
title_fullStr FeNi(3) magnetic nanoparticles supported on ruthenium silicate-functionalized DFNS for photocatalytic CO(2) reduction to formate
title_full_unstemmed FeNi(3) magnetic nanoparticles supported on ruthenium silicate-functionalized DFNS for photocatalytic CO(2) reduction to formate
title_short FeNi(3) magnetic nanoparticles supported on ruthenium silicate-functionalized DFNS for photocatalytic CO(2) reduction to formate
title_sort feni(3) magnetic nanoparticles supported on ruthenium silicate-functionalized dfns for photocatalytic co(2) reduction to formate
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054344/
https://www.ncbi.nlm.nih.gov/pubmed/35517733
http://dx.doi.org/10.1039/d0ra03928d
work_keys_str_mv AT abeadinader feni3magneticnanoparticlessupportedonrutheniumsilicatefunctionalizeddfnsforphotocatalyticco2reductiontoformate
AT zhianirahele feni3magneticnanoparticlessupportedonrutheniumsilicatefunctionalizeddfnsforphotocatalyticco2reductiontoformate
AT motavalizadehkakhkyalireza feni3magneticnanoparticlessupportedonrutheniumsilicatefunctionalizeddfnsforphotocatalyticco2reductiontoformate
AT omidwarmaryam feni3magneticnanoparticlessupportedonrutheniumsilicatefunctionalizeddfnsforphotocatalyticco2reductiontoformate
AT hosseinymalihesadat feni3magneticnanoparticlessupportedonrutheniumsilicatefunctionalizeddfnsforphotocatalyticco2reductiontoformate

Ejemplares similares