Photodynamic properties of tungsten iodide clusters incorporated into silicone: A(2)[M(6)I(8)L(6)]@silicone

The light-induced antibacterial and antifungal properties of A(2)[M(6)I(8)L(6)] with M = Mo and W, A = organic cation, L = ligand have been studied. The photoactive compounds (TBA)(2)[W(6)I(8)(C(7)H(7)SO(3))(6)] and (TBA)(2)[W(6)I(8)(COOCF(3))(6)] have been incorporated into a permeable silicone mat...

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Detalles Bibliográficos
Autores principales: Hummel, Thorsten, Dutczak, Danuta, Alekseev, Alexander Y., Adamenko, Lyubov S., Shestopalov, Michael A., Mironov, Yuri V., Enseling, David, Jüstel, Thomas, Meyer, Hans-Jürgen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054561/
https://www.ncbi.nlm.nih.gov/pubmed/35516606
http://dx.doi.org/10.1039/d0ra04280c
Descripción
Sumario:The light-induced antibacterial and antifungal properties of A(2)[M(6)I(8)L(6)] with M = Mo and W, A = organic cation, L = ligand have been studied. The photoactive compounds (TBA)(2)[W(6)I(8)(C(7)H(7)SO(3))(6)] and (TBA)(2)[W(6)I(8)(COOCF(3))(6)] have been incorporated into a permeable silicone matrix and were measured for their application in the decomposition of multi-resistant bioactive species (hospital germs) such as S. aureus and P. aeruginosa as well as fungi. In addition, we present a new high volume synthesis route for these types of cluster compounds departing from the soluble compound W(6)I(22).

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