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Pyroelectric synthesis of Au/Pt bimetallic nanoparticles–BaTiO(3) hybrid nanomaterials
This paper introduces an approach to synthesize bimetallic nanoparticles under an alternating temperature field in aqueous solution. During the synthesis, pyro-catalytic barium titanate is used as the substrate to reduce the metallic ions dispersed in the solution due to the generated charges at the...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054579/ https://www.ncbi.nlm.nih.gov/pubmed/35514593 http://dx.doi.org/10.1039/d0ra00648c |
Sumario: | This paper introduces an approach to synthesize bimetallic nanoparticles under an alternating temperature field in aqueous solution. During the synthesis, pyro-catalytic barium titanate is used as the substrate to reduce the metallic ions dispersed in the solution due to the generated charges at the surface of pyro-materials under temperature oscillation. Chloroauric acid and potassium tetrachloroplatinate are used as precursors to produce gold/platinum bimetallic nanoparticles through a pyro-catalytic process. Transmission electron microscopy characterization, in combination with energy dispersive X-ray spectroscopy mapping, demonstrates that the bimetallic nanoparticle is composed of an Au core and Au/Pt alloy shell structure. Compared to the conventional approaches, the pyroelectric synthesis approach demonstrated in this work requires no toxic reducing agents and waste heat can be used as a thermal energy source in the synthesis. Hence, it offers a potential “green” synthetic method for bimetallic nanoparticles. |
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