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Electromagnetic and microwave absorption properties of iron pentacarbonyl pyrolysis-synthesized carbonyl iron fibers

The present study executed iron pentacarbonyl pyrolysis to synthesize one-dimensional structured carbonyl iron fibers (CIFs) via carrier gas induced flow. The obtained CIFs with a diameter of 100–300 nm and length–diameter ratio of more than 20, are actually composed of a large number of nanocrystal...

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Autores principales: Ge, Chaoqun, Wang, Liuying, Liu, Gu, Xu, Kejun, Wang, Long, Zhang, Lei, He, Xuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055101/
https://www.ncbi.nlm.nih.gov/pubmed/35517347
http://dx.doi.org/10.1039/d0ra00222d
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author Ge, Chaoqun
Wang, Liuying
Liu, Gu
Xu, Kejun
Wang, Long
Zhang, Lei
He, Xuan
author_facet Ge, Chaoqun
Wang, Liuying
Liu, Gu
Xu, Kejun
Wang, Long
Zhang, Lei
He, Xuan
author_sort Ge, Chaoqun
collection PubMed
description The present study executed iron pentacarbonyl pyrolysis to synthesize one-dimensional structured carbonyl iron fibers (CIFs) via carrier gas induced flow. The obtained CIFs with a diameter of 100–300 nm and length–diameter ratio of more than 20, are actually composed of a large number of nanocrystalline aggregates. We investigated the dependence of the structure, morphology, and static magnetic and electromagnetic properties of the CIFs on the pyrolysis temperatures. CIFs synthesized at 300 °C (denoted as CIF-300) exhibited optimal microwave absorption properties dependent on the fiber structure and well-matched impedance. An optimal reflection loss of −58.1 dB was observed at 13.8 GHz with a matching thickness of 1.43 mm. Furthermore, CIF-300 presented a broad effective absorption bandwidth (RL ≤ −10 dB) of 5.66 GHz with a thickness of 1.44 mm, indicating that it could be applied in practical applications from 3.74 GHz to 18.0 GHz by tuning its thickness from 1.0 mm to 4.0 mm. This paper not only reveals that the CIFs synthesized at 300 °C have great potential application in microwave absorbing materials (MAMs) with thin thicknesses, wide absorption bandwidths, and strong absorption intensities, but also provides a simple approach to prepare metal fibers.
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spelling pubmed-90551012022-05-04 Electromagnetic and microwave absorption properties of iron pentacarbonyl pyrolysis-synthesized carbonyl iron fibers Ge, Chaoqun Wang, Liuying Liu, Gu Xu, Kejun Wang, Long Zhang, Lei He, Xuan RSC Adv Chemistry The present study executed iron pentacarbonyl pyrolysis to synthesize one-dimensional structured carbonyl iron fibers (CIFs) via carrier gas induced flow. The obtained CIFs with a diameter of 100–300 nm and length–diameter ratio of more than 20, are actually composed of a large number of nanocrystalline aggregates. We investigated the dependence of the structure, morphology, and static magnetic and electromagnetic properties of the CIFs on the pyrolysis temperatures. CIFs synthesized at 300 °C (denoted as CIF-300) exhibited optimal microwave absorption properties dependent on the fiber structure and well-matched impedance. An optimal reflection loss of −58.1 dB was observed at 13.8 GHz with a matching thickness of 1.43 mm. Furthermore, CIF-300 presented a broad effective absorption bandwidth (RL ≤ −10 dB) of 5.66 GHz with a thickness of 1.44 mm, indicating that it could be applied in practical applications from 3.74 GHz to 18.0 GHz by tuning its thickness from 1.0 mm to 4.0 mm. This paper not only reveals that the CIFs synthesized at 300 °C have great potential application in microwave absorbing materials (MAMs) with thin thicknesses, wide absorption bandwidths, and strong absorption intensities, but also provides a simple approach to prepare metal fibers. The Royal Society of Chemistry 2020-06-22 /pmc/articles/PMC9055101/ /pubmed/35517347 http://dx.doi.org/10.1039/d0ra00222d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Ge, Chaoqun
Wang, Liuying
Liu, Gu
Xu, Kejun
Wang, Long
Zhang, Lei
He, Xuan
Electromagnetic and microwave absorption properties of iron pentacarbonyl pyrolysis-synthesized carbonyl iron fibers
title Electromagnetic and microwave absorption properties of iron pentacarbonyl pyrolysis-synthesized carbonyl iron fibers
title_full Electromagnetic and microwave absorption properties of iron pentacarbonyl pyrolysis-synthesized carbonyl iron fibers
title_fullStr Electromagnetic and microwave absorption properties of iron pentacarbonyl pyrolysis-synthesized carbonyl iron fibers
title_full_unstemmed Electromagnetic and microwave absorption properties of iron pentacarbonyl pyrolysis-synthesized carbonyl iron fibers
title_short Electromagnetic and microwave absorption properties of iron pentacarbonyl pyrolysis-synthesized carbonyl iron fibers
title_sort electromagnetic and microwave absorption properties of iron pentacarbonyl pyrolysis-synthesized carbonyl iron fibers
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055101/
https://www.ncbi.nlm.nih.gov/pubmed/35517347
http://dx.doi.org/10.1039/d0ra00222d
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