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Large interlayer spacing Nb(4)C(3)T(x) (MXene) promotes the ultrasensitive electrochemical detection of Pb(2+) on glassy carbon electrodes

A Nb(4)C(3)T(x) (MXene)-modified glassy carbon electrode was used for the electrochemical detection of Pb(2+) ions in aqueous media. The sensing platform was evaluated by anodic stripping analysis after optimizing the influencing factors such as pH, deposition potential, and time. The large interlay...

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Autores principales: Rasheed, P. Abdul, Pandey, Ravi P., Gomez, Tricia, Naguib, Michael, Mahmoud, Khaled A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055209/
https://www.ncbi.nlm.nih.gov/pubmed/35516227
http://dx.doi.org/10.1039/d0ra04377j
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author Rasheed, P. Abdul
Pandey, Ravi P.
Gomez, Tricia
Naguib, Michael
Mahmoud, Khaled A.
author_facet Rasheed, P. Abdul
Pandey, Ravi P.
Gomez, Tricia
Naguib, Michael
Mahmoud, Khaled A.
author_sort Rasheed, P. Abdul
collection PubMed
description A Nb(4)C(3)T(x) (MXene)-modified glassy carbon electrode was used for the electrochemical detection of Pb(2+) ions in aqueous media. The sensing platform was evaluated by anodic stripping analysis after optimizing the influencing factors such as pH, deposition potential, and time. The large interlayer spacing, high c lattice parameter and higher conductivity of Nb(4)C(3)T(x) compared to other MXenes enhance the electrochemical detection of Pb(2+). The developed sensor can reach a detection limit of 12 nM at a potential ∼−0.6 V. Additionally, the developed sensor showed promising selectivity in the presence of Cu(2+) and Cd(2+), and stability for at least 5 cycles of continuous measurements with good repeatability. This work demonstrates the potential applications of Nb(4)C(3)T(x) towards the development of effective electrochemical sensors.
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spelling pubmed-90552092022-05-04 Large interlayer spacing Nb(4)C(3)T(x) (MXene) promotes the ultrasensitive electrochemical detection of Pb(2+) on glassy carbon electrodes Rasheed, P. Abdul Pandey, Ravi P. Gomez, Tricia Naguib, Michael Mahmoud, Khaled A. RSC Adv Chemistry A Nb(4)C(3)T(x) (MXene)-modified glassy carbon electrode was used for the electrochemical detection of Pb(2+) ions in aqueous media. The sensing platform was evaluated by anodic stripping analysis after optimizing the influencing factors such as pH, deposition potential, and time. The large interlayer spacing, high c lattice parameter and higher conductivity of Nb(4)C(3)T(x) compared to other MXenes enhance the electrochemical detection of Pb(2+). The developed sensor can reach a detection limit of 12 nM at a potential ∼−0.6 V. Additionally, the developed sensor showed promising selectivity in the presence of Cu(2+) and Cd(2+), and stability for at least 5 cycles of continuous measurements with good repeatability. This work demonstrates the potential applications of Nb(4)C(3)T(x) towards the development of effective electrochemical sensors. The Royal Society of Chemistry 2020-06-29 /pmc/articles/PMC9055209/ /pubmed/35516227 http://dx.doi.org/10.1039/d0ra04377j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Rasheed, P. Abdul
Pandey, Ravi P.
Gomez, Tricia
Naguib, Michael
Mahmoud, Khaled A.
Large interlayer spacing Nb(4)C(3)T(x) (MXene) promotes the ultrasensitive electrochemical detection of Pb(2+) on glassy carbon electrodes
title Large interlayer spacing Nb(4)C(3)T(x) (MXene) promotes the ultrasensitive electrochemical detection of Pb(2+) on glassy carbon electrodes
title_full Large interlayer spacing Nb(4)C(3)T(x) (MXene) promotes the ultrasensitive electrochemical detection of Pb(2+) on glassy carbon electrodes
title_fullStr Large interlayer spacing Nb(4)C(3)T(x) (MXene) promotes the ultrasensitive electrochemical detection of Pb(2+) on glassy carbon electrodes
title_full_unstemmed Large interlayer spacing Nb(4)C(3)T(x) (MXene) promotes the ultrasensitive electrochemical detection of Pb(2+) on glassy carbon electrodes
title_short Large interlayer spacing Nb(4)C(3)T(x) (MXene) promotes the ultrasensitive electrochemical detection of Pb(2+) on glassy carbon electrodes
title_sort large interlayer spacing nb(4)c(3)t(x) (mxene) promotes the ultrasensitive electrochemical detection of pb(2+) on glassy carbon electrodes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055209/
https://www.ncbi.nlm.nih.gov/pubmed/35516227
http://dx.doi.org/10.1039/d0ra04377j
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