Globally stabilized bent carbon–carbon triple bond by hydrogen-free inorganic–metallic scaffolding Al(4)F(6)

For over 100 years, known bent C[triple bond, length as m-dash]C compounds have been limited to those with organic (I) and all-carbon (II) scaffoldings. Here, we computationally report a novel type (III) of bent C[triple bond, length as m-dash]C compound, i.e., C(2)Al(4)F(6)-01, which is the energet...

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Detalles Bibliográficos
Autores principales: Xue, Ying-ying, Zhang, Ying, Cui, Zhong-hua, Ding, Yi-hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055247/
https://www.ncbi.nlm.nih.gov/pubmed/35517486
http://dx.doi.org/10.1039/d0ra02280b
Descripción
Sumario:For over 100 years, known bent C[triple bond, length as m-dash]C compounds have been limited to those with organic (I) and all-carbon (II) scaffoldings. Here, we computationally report a novel type (III) of bent C[triple bond, length as m-dash]C compound, i.e., C(2)Al(4)F(6)-01, which is the energetically global minimum isomer and bears an inorganic–metallic scaffolding and unexpected click reactivity.

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