Globally stabilized bent carbon–carbon triple bond by hydrogen-free inorganic–metallic scaffolding Al(4)F(6)

For over 100 years, known bent C[triple bond, length as m-dash]C compounds have been limited to those with organic (I) and all-carbon (II) scaffoldings. Here, we computationally report a novel type (III) of bent C[triple bond, length as m-dash]C compound, i.e., C(2)Al(4)F(6)-01, which is the energet...

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Detalles Bibliográficos
Autores principales: Xue, Ying-ying, Zhang, Ying, Cui, Zhong-hua, Ding, Yi-hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055247/
https://www.ncbi.nlm.nih.gov/pubmed/35517486
http://dx.doi.org/10.1039/d0ra02280b
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author Xue, Ying-ying
Zhang, Ying
Cui, Zhong-hua
Ding, Yi-hong
author_facet Xue, Ying-ying
Zhang, Ying
Cui, Zhong-hua
Ding, Yi-hong
author_sort Xue, Ying-ying
collection PubMed
description For over 100 years, known bent C[triple bond, length as m-dash]C compounds have been limited to those with organic (I) and all-carbon (II) scaffoldings. Here, we computationally report a novel type (III) of bent C[triple bond, length as m-dash]C compound, i.e., C(2)Al(4)F(6)-01, which is the energetically global minimum isomer and bears an inorganic–metallic scaffolding and unexpected click reactivity.
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spelling pubmed-90552472022-05-04 Globally stabilized bent carbon–carbon triple bond by hydrogen-free inorganic–metallic scaffolding Al(4)F(6) Xue, Ying-ying Zhang, Ying Cui, Zhong-hua Ding, Yi-hong RSC Adv Chemistry For over 100 years, known bent C[triple bond, length as m-dash]C compounds have been limited to those with organic (I) and all-carbon (II) scaffoldings. Here, we computationally report a novel type (III) of bent C[triple bond, length as m-dash]C compound, i.e., C(2)Al(4)F(6)-01, which is the energetically global minimum isomer and bears an inorganic–metallic scaffolding and unexpected click reactivity. The Royal Society of Chemistry 2020-07-03 /pmc/articles/PMC9055247/ /pubmed/35517486 http://dx.doi.org/10.1039/d0ra02280b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Xue, Ying-ying
Zhang, Ying
Cui, Zhong-hua
Ding, Yi-hong
Globally stabilized bent carbon–carbon triple bond by hydrogen-free inorganic–metallic scaffolding Al(4)F(6)
title Globally stabilized bent carbon–carbon triple bond by hydrogen-free inorganic–metallic scaffolding Al(4)F(6)
title_full Globally stabilized bent carbon–carbon triple bond by hydrogen-free inorganic–metallic scaffolding Al(4)F(6)
title_fullStr Globally stabilized bent carbon–carbon triple bond by hydrogen-free inorganic–metallic scaffolding Al(4)F(6)
title_full_unstemmed Globally stabilized bent carbon–carbon triple bond by hydrogen-free inorganic–metallic scaffolding Al(4)F(6)
title_short Globally stabilized bent carbon–carbon triple bond by hydrogen-free inorganic–metallic scaffolding Al(4)F(6)
title_sort globally stabilized bent carbon–carbon triple bond by hydrogen-free inorganic–metallic scaffolding al(4)f(6)
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055247/
https://www.ncbi.nlm.nih.gov/pubmed/35517486
http://dx.doi.org/10.1039/d0ra02280b
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