Synthesis of cobalt tetra-2,3-pyridiniumporphyrazinato with sulfonic acid tags as an efficient catalyst and its application for the synthesis of bicyclic ortho-aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines

Cobalt tetra-2,3-pyridiniumporphyrazinato with sulfonic acid tag [Co(TPPASO(3)H)]Cl was produced and catalyzed the synthesis of ortho-aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines. The synthesis of 2-amino-3-cyanopyridines by using [Co(TPPASO(3)H)]Cl proceeded via a coope...

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Autores principales: Dashteh, Mohammad, Zolfigol, Mohammad Ali, Khazaei, Ardeshir, Baghery, Saeed, Yarie, Meysam, Makhdoomi, Sajjad, Safaiee, Maliheh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055596/
https://www.ncbi.nlm.nih.gov/pubmed/35516925
http://dx.doi.org/10.1039/d0ra02172e
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author Dashteh, Mohammad
Zolfigol, Mohammad Ali
Khazaei, Ardeshir
Baghery, Saeed
Yarie, Meysam
Makhdoomi, Sajjad
Safaiee, Maliheh
author_facet Dashteh, Mohammad
Zolfigol, Mohammad Ali
Khazaei, Ardeshir
Baghery, Saeed
Yarie, Meysam
Makhdoomi, Sajjad
Safaiee, Maliheh
author_sort Dashteh, Mohammad
collection PubMed
description Cobalt tetra-2,3-pyridiniumporphyrazinato with sulfonic acid tag [Co(TPPASO(3)H)]Cl was produced and catalyzed the synthesis of ortho-aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines. The synthesis of 2-amino-3-cyanopyridines by using [Co(TPPASO(3)H)]Cl proceeded via a cooperative vinylogous anomeric based oxidation mechanism. [Co(TPPASO(3)H)]Cl can be recycled and reused six times with a marginal decreasing of its catalytic activity.
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spelling pubmed-90555962022-05-04 Synthesis of cobalt tetra-2,3-pyridiniumporphyrazinato with sulfonic acid tags as an efficient catalyst and its application for the synthesis of bicyclic ortho-aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines Dashteh, Mohammad Zolfigol, Mohammad Ali Khazaei, Ardeshir Baghery, Saeed Yarie, Meysam Makhdoomi, Sajjad Safaiee, Maliheh RSC Adv Chemistry Cobalt tetra-2,3-pyridiniumporphyrazinato with sulfonic acid tag [Co(TPPASO(3)H)]Cl was produced and catalyzed the synthesis of ortho-aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines. The synthesis of 2-amino-3-cyanopyridines by using [Co(TPPASO(3)H)]Cl proceeded via a cooperative vinylogous anomeric based oxidation mechanism. [Co(TPPASO(3)H)]Cl can be recycled and reused six times with a marginal decreasing of its catalytic activity. The Royal Society of Chemistry 2020-07-24 /pmc/articles/PMC9055596/ /pubmed/35516925 http://dx.doi.org/10.1039/d0ra02172e Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Dashteh, Mohammad
Zolfigol, Mohammad Ali
Khazaei, Ardeshir
Baghery, Saeed
Yarie, Meysam
Makhdoomi, Sajjad
Safaiee, Maliheh
Synthesis of cobalt tetra-2,3-pyridiniumporphyrazinato with sulfonic acid tags as an efficient catalyst and its application for the synthesis of bicyclic ortho-aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines
title Synthesis of cobalt tetra-2,3-pyridiniumporphyrazinato with sulfonic acid tags as an efficient catalyst and its application for the synthesis of bicyclic ortho-aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines
title_full Synthesis of cobalt tetra-2,3-pyridiniumporphyrazinato with sulfonic acid tags as an efficient catalyst and its application for the synthesis of bicyclic ortho-aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines
title_fullStr Synthesis of cobalt tetra-2,3-pyridiniumporphyrazinato with sulfonic acid tags as an efficient catalyst and its application for the synthesis of bicyclic ortho-aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines
title_full_unstemmed Synthesis of cobalt tetra-2,3-pyridiniumporphyrazinato with sulfonic acid tags as an efficient catalyst and its application for the synthesis of bicyclic ortho-aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines
title_short Synthesis of cobalt tetra-2,3-pyridiniumporphyrazinato with sulfonic acid tags as an efficient catalyst and its application for the synthesis of bicyclic ortho-aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines
title_sort synthesis of cobalt tetra-2,3-pyridiniumporphyrazinato with sulfonic acid tags as an efficient catalyst and its application for the synthesis of bicyclic ortho-aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055596/
https://www.ncbi.nlm.nih.gov/pubmed/35516925
http://dx.doi.org/10.1039/d0ra02172e
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