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K(2)S(2)O(8)-promoted C–Se bond formation to construct α-phenylseleno carbonyl compounds and α,β-unsaturated carbonyl compounds
A novel K(2)S(2)O(8)-promoted C–Se bond formation from cross-coupling under neutral conditions has been developed. A variety of aldehydes and ketones react well using K(2)S(2)O(8) as the oxidant in the absence of catalyst and afford desired products in moderate to excellent yields. This protocol pro...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055883/ https://www.ncbi.nlm.nih.gov/pubmed/35520078 http://dx.doi.org/10.1039/d0ra05927g |
| _version_ | 1784697512882339840 |
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| author | Yang, Xue-Yan Wang, Ruizhe Wang, Lu Li, Jianjun Mao, Shuai Zhang, San-Qi Chen, Nanzheng |
| author_facet | Yang, Xue-Yan Wang, Ruizhe Wang, Lu Li, Jianjun Mao, Shuai Zhang, San-Qi Chen, Nanzheng |
| author_sort | Yang, Xue-Yan |
| collection | PubMed |
| description | A novel K(2)S(2)O(8)-promoted C–Se bond formation from cross-coupling under neutral conditions has been developed. A variety of aldehydes and ketones react well using K(2)S(2)O(8) as the oxidant in the absence of catalyst and afford desired products in moderate to excellent yields. This protocol provides a very simple route for the synthesis of α-phenylseleno carbonyl compounds and α,β-unsaturated carbonyl compounds. |
| format | Online Article Text |
| id | pubmed-9055883 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2020 |
| publisher | The Royal Society of Chemistry |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-90558832022-05-04 K(2)S(2)O(8)-promoted C–Se bond formation to construct α-phenylseleno carbonyl compounds and α,β-unsaturated carbonyl compounds Yang, Xue-Yan Wang, Ruizhe Wang, Lu Li, Jianjun Mao, Shuai Zhang, San-Qi Chen, Nanzheng RSC Adv Chemistry A novel K(2)S(2)O(8)-promoted C–Se bond formation from cross-coupling under neutral conditions has been developed. A variety of aldehydes and ketones react well using K(2)S(2)O(8) as the oxidant in the absence of catalyst and afford desired products in moderate to excellent yields. This protocol provides a very simple route for the synthesis of α-phenylseleno carbonyl compounds and α,β-unsaturated carbonyl compounds. The Royal Society of Chemistry 2020-08-05 /pmc/articles/PMC9055883/ /pubmed/35520078 http://dx.doi.org/10.1039/d0ra05927g Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
| spellingShingle | Chemistry Yang, Xue-Yan Wang, Ruizhe Wang, Lu Li, Jianjun Mao, Shuai Zhang, San-Qi Chen, Nanzheng K(2)S(2)O(8)-promoted C–Se bond formation to construct α-phenylseleno carbonyl compounds and α,β-unsaturated carbonyl compounds |
| title | K(2)S(2)O(8)-promoted C–Se bond formation to construct α-phenylseleno carbonyl compounds and α,β-unsaturated carbonyl compounds |
| title_full | K(2)S(2)O(8)-promoted C–Se bond formation to construct α-phenylseleno carbonyl compounds and α,β-unsaturated carbonyl compounds |
| title_fullStr | K(2)S(2)O(8)-promoted C–Se bond formation to construct α-phenylseleno carbonyl compounds and α,β-unsaturated carbonyl compounds |
| title_full_unstemmed | K(2)S(2)O(8)-promoted C–Se bond formation to construct α-phenylseleno carbonyl compounds and α,β-unsaturated carbonyl compounds |
| title_short | K(2)S(2)O(8)-promoted C–Se bond formation to construct α-phenylseleno carbonyl compounds and α,β-unsaturated carbonyl compounds |
| title_sort | k(2)s(2)o(8)-promoted c–se bond formation to construct α-phenylseleno carbonyl compounds and α,β-unsaturated carbonyl compounds |
| topic | Chemistry |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055883/ https://www.ncbi.nlm.nih.gov/pubmed/35520078 http://dx.doi.org/10.1039/d0ra05927g |
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