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Efficient electrocatalyst of α-Fe(2)O(3) nanorings for oxygen evolution reaction in acidic conditions

Large-scale application of sustainable energy devices urgently requires cost-effective electrocatalysts to overcome the sluggish kinetics related to the oxygen evolution reaction (OER) under acidic conditions. Here, we first report the highly efficient electrocatalytic characteristics of α-Fe(2)O(3)...

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Detalles Bibliográficos
Autores principales: Liang, Xiaolei, Qian, Jinmei, Liu, Yonggang, Zhang, Zhengmei, Gao, Daqiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055951/
https://www.ncbi.nlm.nih.gov/pubmed/35521123
http://dx.doi.org/10.1039/d0ra04262e
Descripción
Sumario:Large-scale application of sustainable energy devices urgently requires cost-effective electrocatalysts to overcome the sluggish kinetics related to the oxygen evolution reaction (OER) under acidic conditions. Here, we first report the highly efficient electrocatalytic characteristics of α-Fe(2)O(3) nanorings (NRs), which exhibits prominent OER electrocatalytic activity with lower overpotential of 1.43 V at 10 mA cm(−2) and great stability in 1 M HCl, surpassing the start-of-the art Ir/C electrocatalyst. The significantly optimized OER activity of the α-Fe(2)O(3) NRs mainly attributes to the synergistic effect of the excellent electrical conductivity and a large effective active surface because of their unique nanoring structure, disordered surface, and the dynamic stability of α-Fe(2)O(3) NRs in acidic conditions.