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Efficient electrocatalyst of α-Fe(2)O(3) nanorings for oxygen evolution reaction in acidic conditions

Large-scale application of sustainable energy devices urgently requires cost-effective electrocatalysts to overcome the sluggish kinetics related to the oxygen evolution reaction (OER) under acidic conditions. Here, we first report the highly efficient electrocatalytic characteristics of α-Fe(2)O(3)...

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Detalles Bibliográficos
Autores principales: Liang, Xiaolei, Qian, Jinmei, Liu, Yonggang, Zhang, Zhengmei, Gao, Daqiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055951/
https://www.ncbi.nlm.nih.gov/pubmed/35521123
http://dx.doi.org/10.1039/d0ra04262e
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author Liang, Xiaolei
Qian, Jinmei
Liu, Yonggang
Zhang, Zhengmei
Gao, Daqiang
author_facet Liang, Xiaolei
Qian, Jinmei
Liu, Yonggang
Zhang, Zhengmei
Gao, Daqiang
author_sort Liang, Xiaolei
collection PubMed
description Large-scale application of sustainable energy devices urgently requires cost-effective electrocatalysts to overcome the sluggish kinetics related to the oxygen evolution reaction (OER) under acidic conditions. Here, we first report the highly efficient electrocatalytic characteristics of α-Fe(2)O(3) nanorings (NRs), which exhibits prominent OER electrocatalytic activity with lower overpotential of 1.43 V at 10 mA cm(−2) and great stability in 1 M HCl, surpassing the start-of-the art Ir/C electrocatalyst. The significantly optimized OER activity of the α-Fe(2)O(3) NRs mainly attributes to the synergistic effect of the excellent electrical conductivity and a large effective active surface because of their unique nanoring structure, disordered surface, and the dynamic stability of α-Fe(2)O(3) NRs in acidic conditions.
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spelling pubmed-90559512022-05-04 Efficient electrocatalyst of α-Fe(2)O(3) nanorings for oxygen evolution reaction in acidic conditions Liang, Xiaolei Qian, Jinmei Liu, Yonggang Zhang, Zhengmei Gao, Daqiang RSC Adv Chemistry Large-scale application of sustainable energy devices urgently requires cost-effective electrocatalysts to overcome the sluggish kinetics related to the oxygen evolution reaction (OER) under acidic conditions. Here, we first report the highly efficient electrocatalytic characteristics of α-Fe(2)O(3) nanorings (NRs), which exhibits prominent OER electrocatalytic activity with lower overpotential of 1.43 V at 10 mA cm(−2) and great stability in 1 M HCl, surpassing the start-of-the art Ir/C electrocatalyst. The significantly optimized OER activity of the α-Fe(2)O(3) NRs mainly attributes to the synergistic effect of the excellent electrical conductivity and a large effective active surface because of their unique nanoring structure, disordered surface, and the dynamic stability of α-Fe(2)O(3) NRs in acidic conditions. The Royal Society of Chemistry 2020-08-06 /pmc/articles/PMC9055951/ /pubmed/35521123 http://dx.doi.org/10.1039/d0ra04262e Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Liang, Xiaolei
Qian, Jinmei
Liu, Yonggang
Zhang, Zhengmei
Gao, Daqiang
Efficient electrocatalyst of α-Fe(2)O(3) nanorings for oxygen evolution reaction in acidic conditions
title Efficient electrocatalyst of α-Fe(2)O(3) nanorings for oxygen evolution reaction in acidic conditions
title_full Efficient electrocatalyst of α-Fe(2)O(3) nanorings for oxygen evolution reaction in acidic conditions
title_fullStr Efficient electrocatalyst of α-Fe(2)O(3) nanorings for oxygen evolution reaction in acidic conditions
title_full_unstemmed Efficient electrocatalyst of α-Fe(2)O(3) nanorings for oxygen evolution reaction in acidic conditions
title_short Efficient electrocatalyst of α-Fe(2)O(3) nanorings for oxygen evolution reaction in acidic conditions
title_sort efficient electrocatalyst of α-fe(2)o(3) nanorings for oxygen evolution reaction in acidic conditions
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055951/
https://www.ncbi.nlm.nih.gov/pubmed/35521123
http://dx.doi.org/10.1039/d0ra04262e
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