Enhanced gas sensing performance of perovskite YFe(1−x)Mn(x)O(3) by doping manganese ions

Perovskite YFe(1−x)Mn(x)O(3) with a hierarchical structure were prepared by a simple hydrothermal method and used as gas sensing materials. The structure, morphology and composition of YFe(1−x)Mn(x)O(3) were investigated using X-ray diffraction, transmission electron microscopy, scanning electron microscopy and X-ray photoelectron spectroscopy. The gas sensing test showed that all YFe(1−x)Mn(x)O(3) perovskites with different Mn doping concentrations displayed fast response and recovery characteristics to multiple analytes as well as good stability and recoverability. With the increase of Mn doping concentration, the response of YFe(1−x)Mn(x)O(3) to four kinds of target atmospheres first increases, then decreases. The sensing performance of YFe(1−x)Mn(x)O(3) is best when x = 0.05. Compared with pure YFeO(3), the responses of YFe(0.95)Mn(0.05)O(3) to 1000 ppm of CH(2)O, C(2)H(6)O, H(2)O(2) and 100% relative humidity were increased by 835%, 1462%, 812% and 801%, respectively. The theoretical detection limit of YFe(0.95)Mn(0.05)O(3) for H(2)O(2) and CH(2)O is 1.75 and 2.55 ppb, respectively. Furthermore, the possibility of buildings a sensor array based on YFe(1−x)Mn(x)O(3) with different doping concentrations was evaluated by principal component analysis and radar chart analysis. It is feasible to realize the visual and discriminative detection of the target analyte by constructing sensor arrays through radar chart analysis and database construction.