Biocompatible ionic liquid [Betaine][H(2)PO(4)] as a reusable catalyst for the substitution of xanthen-9-ol under solvent-free conditions

An ionic liquid, namely [Betaine][H(2)PO(4)], was found to be an efficient catalyst for the direct substitution reaction of xanthen-9-ol with different nucleophiles under solvent-free conditions. This catalytic system is easy to be operated and the following work-up procedure is simple, with the ion...

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Detalles Bibliográficos
Autores principales: Zhu, Anlian, Wang, Tong, Feng, Wanlu, Wang, Jianji, Li, Lingjun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056413/
https://www.ncbi.nlm.nih.gov/pubmed/35520689
http://dx.doi.org/10.1039/d0ra05374k
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author Zhu, Anlian
Wang, Tong
Feng, Wanlu
Wang, Jianji
Li, Lingjun
author_facet Zhu, Anlian
Wang, Tong
Feng, Wanlu
Wang, Jianji
Li, Lingjun
author_sort Zhu, Anlian
collection PubMed
description An ionic liquid, namely [Betaine][H(2)PO(4)], was found to be an efficient catalyst for the direct substitution reaction of xanthen-9-ol with different nucleophiles under solvent-free conditions. This catalytic system is easy to be operated and the following work-up procedure is simple, with the ionic liquid catalyst reusable for at least five cycles at a high catalytic activity level. In addition, the ionic liquid is easy to prepare and its raw materials are inexpensive and have good biocompatibility. Therefore, our study presents an intriguing and sustainable protocol for the direct substitution of alcohol.
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spelling pubmed-90564132022-05-04 Biocompatible ionic liquid [Betaine][H(2)PO(4)] as a reusable catalyst for the substitution of xanthen-9-ol under solvent-free conditions Zhu, Anlian Wang, Tong Feng, Wanlu Wang, Jianji Li, Lingjun RSC Adv Chemistry An ionic liquid, namely [Betaine][H(2)PO(4)], was found to be an efficient catalyst for the direct substitution reaction of xanthen-9-ol with different nucleophiles under solvent-free conditions. This catalytic system is easy to be operated and the following work-up procedure is simple, with the ionic liquid catalyst reusable for at least five cycles at a high catalytic activity level. In addition, the ionic liquid is easy to prepare and its raw materials are inexpensive and have good biocompatibility. Therefore, our study presents an intriguing and sustainable protocol for the direct substitution of alcohol. The Royal Society of Chemistry 2020-08-27 /pmc/articles/PMC9056413/ /pubmed/35520689 http://dx.doi.org/10.1039/d0ra05374k Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Zhu, Anlian
Wang, Tong
Feng, Wanlu
Wang, Jianji
Li, Lingjun
Biocompatible ionic liquid [Betaine][H(2)PO(4)] as a reusable catalyst for the substitution of xanthen-9-ol under solvent-free conditions
title Biocompatible ionic liquid [Betaine][H(2)PO(4)] as a reusable catalyst for the substitution of xanthen-9-ol under solvent-free conditions
title_full Biocompatible ionic liquid [Betaine][H(2)PO(4)] as a reusable catalyst for the substitution of xanthen-9-ol under solvent-free conditions
title_fullStr Biocompatible ionic liquid [Betaine][H(2)PO(4)] as a reusable catalyst for the substitution of xanthen-9-ol under solvent-free conditions
title_full_unstemmed Biocompatible ionic liquid [Betaine][H(2)PO(4)] as a reusable catalyst for the substitution of xanthen-9-ol under solvent-free conditions
title_short Biocompatible ionic liquid [Betaine][H(2)PO(4)] as a reusable catalyst for the substitution of xanthen-9-ol under solvent-free conditions
title_sort biocompatible ionic liquid [betaine][h(2)po(4)] as a reusable catalyst for the substitution of xanthen-9-ol under solvent-free conditions
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056413/
https://www.ncbi.nlm.nih.gov/pubmed/35520689
http://dx.doi.org/10.1039/d0ra05374k
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