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Heterodinuclear nickel(ii)–iron(ii) azadithiolates as structural and functional models for the active site of [NiFe]-hydrogenases
To develop the biomimetic chemistry of [NiFe]-H(2)ases, the first azadithiolato-bridged NiFe model complexes [CpNi{(μ-SCH(2))(2)NR}Fe(CO)(diphos)]BF(4) (5, R = Ph, diphos = dppv; 6, 4-ClC(6)H(4), dppv; 7, 4-MeC(6)H(4), dppv; 8, CO(2)CH(2)Ph, dppe; 9, H, dppe) have been synthesized via well-designed...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056516/ https://www.ncbi.nlm.nih.gov/pubmed/35518169 http://dx.doi.org/10.1039/d0ra04344c |