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Unraveling the kinetics and molecular mechanism of gas phase pyrolysis of cubane to [8]annulene
The kinetic and electron density flows are studied theoretically for the gas phase pyrolysis of cubane via its cage opening to reach bicyclooctatriene and then thermal rearrangement of bicyclooctatriene to produce [8]annulene which is the experimentally observed major product. The observed kinetic d...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9056628/ https://www.ncbi.nlm.nih.gov/pubmed/35516465 http://dx.doi.org/10.1039/d0ra05371f |